3175-89-1 Usage
Uses
Used in Pharmaceutical Industry:
USHINSUNINE is used as a pharmaceutical compound for its potential therapeutic applications. The expression is: USHINSUNINE is used as a pharmaceutical compound for its potential therapeutic applications.
Used in Chemical Research:
USHINSUNINE is used as a research compound in the field of chemical research, particularly in the study of aporphine alkaloids and their properties. The expression is: USHINSUNINE is used as a research compound for the study of aporphine alkaloids and their properties.
Used in Natural Product Extraction:
USHINSUNINE is used in the extraction and isolation of natural products from plant sources, such as Michelia alba, M. champaca, and M. compressa. The expression is: USHINSUNINE is used in the extraction and isolation of natural products from plant sources.
References
Tomita, Furukawa., J. Pharm. Soc., Japan, 82, 925 (1962)
Yang et al., ibid, 82, 794, 798, 804, 811 (1962)
Yang et al., ibid, 83,216 (1963)
Absolute configuration:
Kunimotoetal., Chem. Pharm. Bull., 19,1502 (1971)
Check Digit Verification of cas no
The CAS Registry Mumber 3175-89-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,1,7 and 5 respectively; the second part has 2 digits, 8 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 3175-89:
(6*3)+(5*1)+(4*7)+(3*5)+(2*8)+(1*9)=91
91 % 10 = 1
So 3175-89-1 is a valid CAS Registry Number.
InChI:InChI=1/C18H17NO3/c1-19-7-6-10-8-13-18(22-9-21-13)15-11-4-2-3-5-12(11)17(20)16(19)14(10)15/h2-5,8,16-17,20H,6-7,9H2,1H3/t16-,17+/m0/s1
3175-89-1Relevant academic research and scientific papers
Diastereoselektive Hydroxyalkylierungen in 1-Stellung von Tetrahydroisochinolinen und Synthese von Aporphin-, Protoberberin- und Phthalid-Alkaloiden
Seebach,Dieter,Huber, Isabelle M. P.,Syfrig, Max A.
, p. 1357 - 1379 (2007/10/02)
Unsubstituted and 6,7-dialkyloxy-N-pivaloyl-tetrahydroisoquinolines 1-3 are converted to 1-bromomagnesium derivatives by sequential treatment with t-BuLi (-75 deg C/THF) and MgBr2*OEt2.Addition of the metalated tetrahydroisoquinolines to aliphatic or arom
Photocyclisation of 1-(2'-Halo-α-hydroxybenzyl)-1,2,3,4-tetrahydroisoquinolines; Synthesis of (+/-)-Oliveridine
Kessar, S. V.,Gupta, Y. P.,Mohammad, Taj
, p. 984 (2007/10/02)
In contrast to α-deoxy analogs, photocyclisation of 1-(2'-halo-α-hydroxybenzyl)-1,2,3,4-tetrahydroisoquinolines to aporphines succeeds even in cyclohexane solvent, probably because of internal hydrogen bonding.A synthesis of the alkaloid oliveridine is de
SYNTHETIC PHOTOCHEMISTRY. SYNTHESIS OF (+/-)OLIVEROLINE AND (+/-)USHINSUNINE
Kessar, S.V.,Gupta, Y.P.,Yadav, V.S.,Narula, Mridu,Mohammad, Taj
, p. 3307 - 3308 (2007/10/02)
Sodium borohydride reduction of 1-(2'-Bromobenzoyl)-2-methyl-3,4-dihydro-6,7-methylenedioxyisoquinolinium iodide (4) gave a mixture of alcohols which on irradiation in dil.HCl afforded (+/-) oliveroline and (+/-) ushinsunine.
