31781-18-7Relevant academic research and scientific papers
Effective transmetalation from gold to iron or ruthenium
Hashmi, A. Stephen K.,Molinari, Lise
, p. 3457 - 3460 (2011/09/12)
The transmetalation of aryl, alkynyl, and alkyl groups from organogold compounds to iron complexes offers an efficient synthesis of organoiron complexes under very mild conditions. This method could be extended to ruthenium complexes.
Arylation of styrenes with aryliron complexes [CpFe(CO)2Ar]
Yasuda, Shigeo,Yorimitsu, Hideki,Oshima, Koichiro
, p. 2634 - 2636 (2010/08/05)
Treatment of aryliron complexes [CpFe(CO)2Ar] with styrenes in boiling xylene affords the corresponding stilbenes. The aryliron complexes, which become active upon heating, serve as arylating agents in the reaction.
Synthesis of functionalized aryliron complexes [CpFe(CO)2Ar] by copper-mediated transmetalation between [CpFe(CO)2I] and aryltin reagents
Yasuda, Shigeo,Yorimitsu, Hideki,Oshima, Koichiro
, p. 273 - 274 (2010/04/04)
Transmetalation between [CpFe(CO)2I] and aryltin reagents in the presence of copper salts yields the corresponding aryliron complexes [CpFe(CO)2Ar]. The high functional group compatibility of this copper-mediated reaction enables us
