3190-78-1

Basic information

• Product Name: Ethanethiol, 2,2'-(phenylphosphinidene)bis-
• CAS NO: 3190-78-1
• Molecular Formula: C10H15PS2
• Molecular Weight: 230.335
• Mol File: 3190-78-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ethanethiol, 2,2'-(phenylphosphinidene)bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanethiol, 2,2'-(phenylphosphinidene)bis-(3190-78-1)
• EPA Substance Registry System: Ethanethiol, 2,2'-(phenylphosphinidene)bis-(3190-78-1)

Safety Data

• Hazardous Substances Data: 3190-78-1(Hazardous Substances Data)

Upstream product

• 157-20-0 ethylene sulphide 
• 638-21-1 phenylphosphane 

Downstream Products

• 116706-22-0 {(C₄H₉)2Sn(SCH₂CH₂)2PC₆H₅}2 
• 101841-58-1 {3-phenyl-3-phosphapentane-1,5-dithiolato^(2-)-S,S',P}-{3-phenyl-3-phosphapentane-1,5-dithiolato^(1-)-S,P}rhenium(III) 
• 78610-88-5 C₆H₅P(CH₂CH₂S)2Sn 
• 200884-71-5 W(C₆H₁₂(PC₆H₅)S₂)(CO)3 
• 107936-85-6 pentacarbonyl-5-phenyl-5-phospha-2,8-dithia-1-stannabicyclo{3.3.0(1.5)}octanechromium⁽⁰⁾ 
• 116706-24-2 {(C₄H₉)2Sn(SCH₂CH₂)2PSeC₆H₅}2 
• 101841-60-5 bis{3-phenyl-3-phosphapentane-1,5-dithiolato^(2-)-S,S',P}tungsten(IV) 
• 147210-31-9 Mo(C₆H₁₂(PC₆H₅)S₂)(CO)3 
• 146719-81-5 1-phenyl-1-phospha-4,7-dithiacyclononane 
• 109-89-7 diethylamine 

Relevant articles and documents

Molybdenum, rhenium, and tungsten complexes with bi- and tri-dentate phosphinothiolato-ligands; structures of 2> and 2>

reacts with two equivalents of Ph2PCH2CH2SH in tetrahydrofuran to give .An excess of tridentate PhP(CH2CH2SH)2 reacts with to yield > containing a pendant unco-ordinated SH group.This complex reacts reversibly with CO to form (CO)> -1>.The MIV complexes 2>.An X-ray crystal-structure determination for the complex with M = Mo shoved a distorted octahedral structure with an average Mo-S distance of 2.44 Aengstroem.The complex crystallises in the triclinic space group P, with a = 10.61(7), b = 10.867(4), c = 12.347(1) Angstroem, α = 85.06(4), γ = 63.0(4) deg, and Z = 2. 1337 Unique reflections with I0 >= 3?(I0) used in the solution converged at R = 0.0979.The hydrazido(2-) complexes Cl react with PhP(CH2CH2SH)2 in MeOH to give 2> (M = Mo or W).An X-ray crystal-structure determination of the complex with M = Mo revealed a distorted pentagonal-bipyramidal structure with a linear apical NNMe2 ligand.The complex crystallises in the monoclinic space group P21/n, with a = 11.349(2), b = 12.403(3), c = 19.302(4) Angstroem, β = 104.28(2) deg, and Z = 4. 2796 Unique reflections with I0 > 3?(I0) used in the solution converged at R = 0.605.