31908-67-5Relevant academic research and scientific papers
SUPERACID ISOMERIZATION OF PHYLLOCLADENE, ISOPHYLLOCLADENE, AND PHYLLOCLADANOL
Vlad, P. F.,Ungur, N. D.,Barba, A. N.,Tatarova, L. E.,Gatilov, Yu. V.,et al.
, p. 301 - 308 (1991)
It has been established that, on interaction with a superacid, phyllocladene (XI), isophyllocladene (XV), and phyllocladan-16-ol (XIX) give identical mixtures of substances which include phyllocladene (XI), isophyllocladene (XV), neoisoatisene (XX), tetracyclic hydrocarbons with a new carbon skeleton (XXI) and (XXII), and a mixture of methyl ethers of alcohols formed as the result of the addition of methanol to the carbocations arising on the protonation of the above-mentioned hydrocarbons.
