Chemistry of Natural Compounds p. 301 - 308 (1991)
Update date:2022-07-30
Topics:
Vlad, P. F.
Ungur, N. D.
Barba, A. N.
Tatarova, L. E.
Gatilov, Yu. V.
et al.
It has been established that, on interaction with a superacid, phyllocladene (XI), isophyllocladene (XV), and phyllocladan-16-ol (XIX) give identical mixtures of substances which include phyllocladene (XI), isophyllocladene (XV), neoisoatisene (XX), tetracyclic hydrocarbons with a new carbon skeleton (XXI) and (XXII), and a mixture of methyl ethers of alcohols formed as the result of the addition of methanol to the carbocations arising on the protonation of the above-mentioned hydrocarbons.
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