319491-83-3

Upstream product

• 54917-60-1 N,N-dibenzyl-1-amino-1-deoxy-D-fructose 
• 319491-81-1 (3aR,6R,7S,7aS)-6-[(Dibenzylamino)-methyl]-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6,7-diol 
• 2280-44-6 D-Glucose 
• 7693-41-6 4-methoxyphenylchloroformate 
• 319491-82-2 (3aR,6R,7S,7aS)-6-Aminomethyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6,7-diol 

Downstream Products

• 403500-98-1 C₂₅H₃₇NO₉Si 
• 403500-96-9 C₂₅H₃₇NO₉Si 
• 403500-94-7 C₂₄H₃₅NO₈Si 
• 403500-92-5 C₂₄H₃₅NO₈Si 
• 403500-90-3 C₂₃H₃₃NO₇Si 
• 403500-82-3 C₂₃H₃₃NO₈Si 
• 403500-80-1 C₂₃H₃₅NO₆Si 
• 403500-99-2 C₁₉H₂₃NO₉ 
• 403500-97-0 C₁₉H₂₃NO₉ 
• 403500-95-8 C₁₈H₂₁NO₈ 
• 403500-93-6 C₁₈H₂₁NO₈ 
• 403500-83-4 C₁₇H₁₉NO₈ 
• 403500-91-4 C₁₇H₁₉NO₇ 
• 403500-81-2 C₁₇H₂₁NO₆ 

Relevant academic research and scientific papers

Designing new chiral ketone catalysts. Asymmetric epoxidation of cis-olefins and terminal olefins

This paper describes a new class of chiral oxazolidinone ketone catalyst for asymmetric epoxidation. High ee values have been obtained for a number of cyclic and acyclic cis-olefins. The epoxidation was stereospecific with no isomerization observed in the epoxidation of acyclic systems. Encouragingly high ee values have also been obtained for a number of terminal olefins. Mechanistic studies show that electronic interactions play an important role in stereodifferentiation.