54917-60-1

Upstream product

• 2280-44-6 D-Glucose 
• 103-49-1 dibenzylamine 

Downstream Products

• 319491-81-1 (3aR,6R,7S,7aS)-6-[(Dibenzylamino)-methyl]-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6,7-diol 
• 492-30-8 2-C-methyl-D-ribono-1,4-lactone 
• 403500-98-1 C₂₅H₃₇NO₉Si 
• 403500-96-9 C₂₅H₃₇NO₉Si 
• 403500-94-7 C₂₄H₃₅NO₈Si 
• 403500-92-5 C₂₄H₃₅NO₈Si 
• 403500-90-3 C₂₃H₃₃NO₇Si 
• 403500-82-3 C₂₃H₃₃NO₈Si 
• 403500-80-1 C₂₃H₃₅NO₆Si 
• 403500-99-2 C₁₉H₂₃NO₉ 
• 403500-97-0 C₁₉H₂₃NO₉ 
• 403500-95-8 C₁₈H₂₁NO₈ 
• 319491-83-3 ((3aR,6R,7S,7aS)-6,7-Dihydroxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-ylmethyl)-carbamic acid 4-methoxy-phenyl ester 
• 403500-93-6 C₁₈H₂₁NO₈ 

Relevant academic research and scientific papers

Designing new chiral ketone catalysts. Asymmetric epoxidation of cis-olefins and terminal olefins

This paper describes a new class of chiral oxazolidinone ketone catalyst for asymmetric epoxidation. High ee values have been obtained for a number of cyclic and acyclic cis-olefins. The epoxidation was stereospecific with no isomerization observed in the epoxidation of acyclic systems. Encouragingly high ee values have also been obtained for a number of terminal olefins. Mechanistic studies show that electronic interactions play an important role in stereodifferentiation.

Amadori ketoses with calcium hydroxide and the Kiliani reaction on 1-deoxy ketoses: Two approaches to the synthesis of saccharinic acids

Saccharinic acids (2-C-methyl aldonic acids) may be formed by treatment of Amadori ketoses with calcium hydroxide or by the Kiliani reaction of 1-deoxy ketoses with cyanide. Thus (i) N,N-dibenzyl or N,N-dimethyl-1-amino-1-deoxy-D- fructose with aqueous ca

An improved synthesis of a ketone catalyst for asymmetric epoxidation of olefins

An efficient synthesis of a ketone catalyst for asymmetric epoxidation of olefins from D-glucose in six steps is described.