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α-Bromobenzoylmethylene triphenylphosphorane is a phosphorus-containing ylide, which is a key intermediate in the Wittig reaction, a widely used method for the synthesis of alkenes. This complex organic molecule consists of a phosphorus atom bonded to three phenyl groups and a carbon-carbon double bond, with one of the carbons also bonded to a bromine atom and a benzoyl group. The molecule is highly reactive due to the presence of the phosphorus-carbon double bond, which can undergo nucleophilic addition reactions with aldehydes and ketones to form carbonyl compounds. Its stability and reactivity make it a valuable tool in organic synthesis, particularly for the preparation of various alkenes and other complex organic molecules.

3201-60-3

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3201-60-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 3201-60-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,2,0 and 1 respectively; the second part has 2 digits, 6 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 3201-60:
(6*3)+(5*2)+(4*0)+(3*1)+(2*6)+(1*0)=43
43 % 10 = 3
So 3201-60-3 is a valid CAS Registry Number.

3201-60-3Relevant academic research and scientific papers

Stereoselective synthesis of α-bromo-α,β-unsaturated ketones via wittig reaction

Huang, Zhizhen,Wang, Lei,Huang, Xian

, p. 757 - 762 (2003)

The synthesis of α-bromo benzoylmethylene triphenylphosphorane 2 is firstly reported and α-bromo ylide 2 has sufficient activity to undergo Wittig reaction, affording a novel method for the stereoselective synthesis of α-bromo-α,β-unsaturated ketones 5.

PYROLYSIS OF α-HALOPHOSPHORANES -> HALOACETYLENES

Braga, Antoenio L.,Comasseto, Joaeo V.

, p. 2877 - 2884 (2007/10/02)

α-Halophosphoranes upon pyrolysis give haloacetylenes in moderate yields.

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