32047-83-9Relevant academic research and scientific papers
Studies in solid state reactions between basic copper carbonate with cinnamic, succinic and adipic acids
Bassi,Chopra,Gupta
, p. 197 - 203 (1988)
Solid-solid reactions of basic copper carbonate with cinnamic, succinic and adipic acids give the corresponding copper(II) carboxylate chelates with the elimination of carbon dioxide and water. Products were characterized by spectral and magnetic studies.
Coordination polymers from mild condition reactions of copper(II) carboxylates with pyrazole (Hpz). Influence of carboxylate basicity on the self-assembly of the [Cu3(μ3-OH)(μ-pz)3]2+secondary building unit
Massignani, Sara,Scatena, Rebecca,Lanza, Arianna,Monari, Magda,Condello, Francesca,Nestola, Fabrizio,Pettinari, Claudio,Zorzi, Federico,Pandolfo, Luciano
, p. 618 - 626 (2016/12/14)
The reaction of some saturated and unsaturated aliphatic copper(II) monocarboxylates, Cu(RCOO)2[R = C6H5CH2(phenylacetate, Phac), CH2[dbnd]CHCH2(vinylacetate, Vnac), C6H5/s
Metal bridging for directing and accelerating electron transfer as exemplified by harnessing the reactivity of AIBN
Xie, Yinjun,Guo, Shengmei,Wu, Longmin,Xia, Chungu,Huang, Hanmin
, p. 5900 - 5904 (2015/05/13)
A new strategy for tuning the electron transfer between radicals and enolates has been developed. This method elicits the innate reactivity of AIBN with a copper catalyst and enables a cascade reaction with cinnamic acids. Electron paramagnetic resonance studies and control experiments indicate that the redox-active copper species not only activates the radical by coordination, but also serves as a bridge to bring the radical and nucleophile within close proximity to facilitate electron transfer. By exploiting possible combinations of redox-active metals and radical entities with suitable coordinating functional groups, this strategy should contribute to the development of a broad range of radical-based reactions.
