320575-04-0

Basic information

• Product Name: (2S,3R)-4-(tert-butyldiphenylsiloxy)-2-(methoxymethoxy)-3-methyl-1-butanol
• Synonyms: (2S,3R)-4-(tert-butyldiphenylsiloxy)-2-(methoxymethoxy)-3-methyl-1-butanol
• CAS NO: 320575-04-0
• Molecular Weight: 402.606
• Mol File: 320575-04-0.mol

Chemical Properties

• CAS DataBase Reference: (2S,3R)-4-(tert-butyldiphenylsiloxy)-2-(methoxymethoxy)-3-methyl-1-butanol(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R)-4-(tert-butyldiphenylsiloxy)-2-(methoxymethoxy)-3-methyl-1-butanol(320575-04-0)
• EPA Substance Registry System: (2S,3R)-4-(tert-butyldiphenylsiloxy)-2-(methoxymethoxy)-3-methyl-1-butanol(320575-04-0)

Safety Data

• Hazardous Substances Data: 320575-04-0(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 95514-04-8 (S)-3-(tert-butyldiphenylsilyloxy)-2-methylpropan-1-ol 
• 107-30-2 chloromethyl methyl ether 
• 320575-07-3 (2S,3R)-4-(tert-Butyl-diphenyl-silanyloxy)-2-hydroxy-3-methyl-butyric acid methyl ester 
• 91751-24-5 (R)-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropanal 

Downstream Products

• 320575-05-1 (2S,3R)-4-(tert-butyldiphenylsiloxy)-2-(methoxymethoxy)-3-methyl-1-butanal 

Relevant articles and documents

A New Polymer-attached Reagent for the Oxidation of Primary and Secondary Alcohols

formula presented A new, polymer-bound reagent system for the efficient oxidation of primary alcohols to aldehydes and secondary alcohols to ketones in the presence of a catalytic amount of 2,2,6,6-tetramethyl-1-piperidinyloxyl (TEMPO) is described. In most cases, workup of this heavy metal-free oxidation is achieved by simple filtration followed by removal of the solvent. In selected examples this reagent was compared with the known polymer-bound permanganate and chromium(VI) reagents.