3206-30-2Relevant academic research and scientific papers
Chemoselective N-acylation of indoles and oxazolidinones with carbonylazoles
Heller, Stephen T.,Schultz, Erica E.,Sarpong, Richmond
supporting information; experimental part, p. 8304 - 8308 (2012/09/08)
Unique reactivity: In the presence of more reactive amine and alcohol functional groups and of carboxylic acids, the chemoselective N-acylation of indoles (see scheme) and oxazolidinones is achieved by taking advantage of the unique reactivity of carbonylazole acylating agents with catalytic amounts of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU). Copyright
Preparation of N-alkoxycarbonyl-substituted cyclic lactams and ketones
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, (2008/06/13)
N-alkoxycarbonyl-substituted cyclic lactams and nitrogen-containing cyclic ketones are prepared by reaction of a C1-20 alkyl ester of trichloroacetic acid with the corresponding cyclic lactam or nitrogen-containing cyclic ketone.
