32084-79-0Relevant academic research and scientific papers
Reversible Ring-opening in the Hydrolysis of Spirophosphoranes
McGall, Glenn H.,McClelland, Robert A.
, p. 560 - 561 (1985)
The spiriphosphorane (1b) (5-phenyloctamethyl-1,4,6,9-tetraoxa-5-phosphaspirononane) undergoes acid-catlysed ligand exchange 107 times faster than acid-catalysed hydrolysis; these two processes have a common phosphonium ion intermediate which has a large preference for reaction with its internal hydroxy group over capture by external water moleczule.
REARRANGEMENTS OF 2-ARYL-4,5-DIPHENYL-1,3,2λ5-DIOXAPHOSPHOLANE 2-OXIDES. STRUCTURE AND PROPERTIES OF ACID BENZOXAPHOSPHORINS
Ovchinnikov, V. V.,Karataeva, F. Kh.,Cherkasov, R. A.
, p. 361 - 373 (2007/10/03)
2-(Halophenyl)-4,5-diphenyl-1,3,2λ5-dioxaphospholane 2-oxides were synthesized, and their irreversible isomerization into acid benzoxaphosphorins, occurring on heating or in a basic medium, was studied.Factors promoting the rearrangement are di
PHOTOLYTIC REARRANGEMENT OF PHOSPHORUS AZIDE : EVIDENCE FOR A TRANSIENT METAPHOSPHONIMIDATE.
Bertrand, Guy,Majoral, Jean-Pierre,Baceiredo, Antoine
, p. 5015 - 5018 (2007/10/02)
Photolysis of the oxide of diphenylphosphine azide gives rise to a transient metaphisphonimidate, a new tricoordinated pentavalent phosphorus compound.Evidence for this species was given by trapping reactions on a variety of substrates.
