321-33-5Relevant academic research and scientific papers
Asymmetric epoxidation of fluoroolefins by chiral dioxirane. Fluorine effect on enantioselectivity
Wong, O. Andrea,Shi, Yian
supporting information; experimental part, p. 8377 - 8380 (2010/03/25)
(Chemical Equation Presented) The asymmetric epoxidation of various fluoroolefins has been studied using chiral ketone catalyst, and up to 93% ee was achieved with fructose-derived ketone 1.
Low-temperature 19F NMR spectroscopy of 1-fluoro-1-lithioethenes - Stability, shifts and unexpected coupling constants
Kvicala, Jaroslav,Hrabal, Richard,Czernek, Jiri,Bartosova, Ivana,Paleta, Oldrich,Pelter, Andrew
, p. 211 - 218 (2007/10/03)
Half-lives and fluorine atom shifts of stabilized 1-fluoro-l-lithioethenes bearing hydrogen, fluorine, phenyl, and/or dimethylphenylsilyl groups in the β-positions have been determined by a low-temperature 19F NMR spectroscopy. Some 1-fluoro-1-lithioethenes displayed an exceptionally low value of the trans-3JFF coupling constant. Stereoselectivity of carbenoid formation, as well as an effect of configuration on the stability is discussed.
Regio- and Stereoselective Synthesis of Fluorinated Enynes and Dienes via 1,1- or 1,2-Halofluoroalkenes
Eddarir, Said,Francesch, Charlette,Mestdagh, Helene,Rolando, Christian
, p. 741 - 756 (2007/10/03)
Monofluorinated enynes and dienes were synthesized stereospecifically through palladium-catalyzed condensation of 1-halo-1-fluoroalkenes or 1-halo-2-fluoroalkenes with monosubstituted alkynes or alkenes, or with allyltributyltin.The various halofluoroalke
Synthesis of fluorinated enynes via 1-bromo 1-fluoro alkenes
Eddarir, Said,Francesch, Charlette,Mestdagh, Helene,Rolando, Christian
, p. 4449 - 4452 (2007/10/02)
A stereospecific synthesis of fluorinated enynes was performed through palladium catalysed condensation of 1-bromo 1-fluoro 2-arylethylenes, synthetised from 1-carboxyl 1-fluoro 2-arylethylene with monosubstitued alkynes.
