321-36-8

Upstream product

• 462-06-6 fluorobenzene 
• 76-02-8 trifluoroacetyl chloride 
• 394-56-9 (+/-)-2,2,2-trichloro-1-(4-fluorophenyl)ethanol 
• 459-57-4 4-fluorobenzaldehyde 

Downstream Products

• 5157-58-4 2,2-dichloro-1-(4-fluorophenyl)-ethan-1-one 
• 339274-32-7 (R)-2,2,2-trichloro-1-(4-fluorophenyl)ethanol 
• 1273584-07-8 (S)-5,5,5-trichloro-4-hydroxy-4-(4-fluorophenyl)pentan-2-one 
• 24843-89-8 (R)-Azido-(4-fluoro-phenyl)-acetic acid 
• 19883-57-9 (S)-2-amino-2-(4-fluorophenyl)acetic acid 

Relevant academic research and scientific papers

PESTICIDAL COMPOUNDS AND METHODS OF USE

Described herein are compounds, pesticidally acceptable salts thereof, and compositions thereof that are useful, for example, for pest management and for controlling pests. In certain embodiments provided are enantioenriched and/or enantiopure compounds and pesticidally acceptable salts thereof, and methods of making same. Methods of controlling pests with the compounds of the disclosure are also provided.

Synthesis of Trihalomethyl Ketones from Trihalomethyl Carbinols (Hal = Cl, Br) Using 2-Iodoxybenzoic Acid

Abstract: An efficient method for the preparation of trihalomethyl (Cl, Br) ketones by the oxidation of trihalomethyl carbinols with 2-iodoxybenzoic acid in tert-butanol under heating has been developed. A series of trihalomethyl ketones have been synthesized through a simple, convenient, and environmentally friendly method with excellent yields.

A practical asymmetric synthesis of homochiral α-arylglycines

Enantioselective reduction of a series of substituted aryl trichloromethyl ketones with the CBS-catecholborane reagent afforded homochiral aryl trichloromethyl carbinols which have been elaborated to give homochiral α-arylglycines in high e.e.