32113-77-2Relevant academic research and scientific papers
Oxidation of an allene compound bearing 1,8-dichloroacridene moieties and photolysis of the halogenated allene compound for the generation of triplet carbenes
Fukuen, Shinichi,Furukawa, Ko,Sasamori, Takahiro,Tokitoh, Norihiro,Abe, Manabu,Yamamoto, Yohsuke
, p. 79 - 87 (2015)
New allene compounds, 5c and 5d, bearing 1,8-dichloroacridene moieties were synthesized, and the oxidation of 5c and 5d was performed to generate thermally stable triplet carbenes. Since the oxidation resulted in the formation of decomposition products, t
Micellar Catalysis of the Basic Hydrolysis of Amides. 4. Substituted N,N-Diphenylbenzamides
Broxton, Trevor J.,Fernando, Denise R.,Rowe, Jeffrey E.
, p. 3522 - 3525 (2007/10/02)
The cytalysis of the basic hydrolysis of a series of N-aryl-N-phenylbenzamides (1) and a series of substituted N,N-diphenylbenzamides (2) by micelles of cetyltrimethylammonium bromide (ctab) has been studied.On the basis of the effects of substituents on the aromatic ring attached to the nitrogen atom, a mechanistic change on transfer from water to a micellar environment is proposed.In water the mechanism involves rate-determining solvent-assisted carbon-nitrogen bond breaking (mechanism B), while in the presence of micelles of ctab, a rate-determining attack of hydroxide ion (mechanism C) is proposed.Reasons for mechanistic change are discussed.
