3217-88-7Relevant academic research and scientific papers
Cross-conjugated compounds: microwave spectrum and ring planarity of 3-methylene-1,4-cyclohexadiene
Hutter, Wolfgang,Bodenseh, Hans-Karl,Koch, Andreas
, p. 73 - 84 (1994)
The unstable 3-methylene-1,4-cyclohexadiene, an isomer of toluene, has been prepared from benzoic acid.The hydrocarbon can be handled quite easily in the solid state, and in the gas phase at low pressures.Rotational transitions have been measured from 12
Conversion of 1,4-Dihydrobenzoic Acids to Polyformylbenzenes under Vilsmeier Reaction Conditions
Raju, B.,Krishna Rao, G. S.
, p. 197 - 199 (2007/10/02)
1,4-Dihydrobenzoic acids 1a-e are converted by a one-pot reaction to benzene- mono-, di- and tricarboxaldehydes under Vilsmeier reaction conditions in yields ranging from 6 to 65percent.The same methodology also serves to give naphthalene-1,3-dicarboxaldehyde (2f) from 1,4-dihydro-1-naphthoic acid (1f) in 91percent yield.
