32174-44-0

Upstream product

• 189816-52-2 (R)-3-Acetoxy-2-phenyl-propionic acid methyl ester 
• 1634-04-4 tert-butyl methyl ether 
• 22979-35-7 Methyl phenyldiazoacetate 
• 189816-47-5 (2R,3Z)-1-acetoxy-2-phenyl-3-octene 
• 189816-44-2 (Z)-(R)-2-Phenyl-oct-3-en-1-ol 
• 131682-38-7 (+)-3-acetoxy-2-phenylpropionic acid 
• 20780-54-5 (S)-styrene oxide 
• 17126-67-9 (+)-(R)-tropic acid 
• 186581-53-3 diazomethane 

Relevant academic research and scientific papers

Influence of a β-Alkoxy Substituent on the C-H Activation Chemistry of Alkyl Ethers

C-H activation reactions of 1,2-dimethoxyethane and methyl tert-butyl ether with methyl aryldiazoacetates or styryldiazoacetate catalyzed by Rh 2(S-DOSP)4 result in the formation of 2-aryl- or 2-styryl-substituted propanoic acids with asymmetric induction up to 95% ee.

A general approach towards 2-substituted 3-hydroxy propanoates; application to the synthesis of methyl tropinate

Enantiomerically pure R or S 2-substituted 3-hydroxy propanoates may be prepared by regioselective BF3 promoted opening of homochiral styrene oxide by lithium cyanocuprates followed by oxidative cleavage of the aromatic moiety with catalytic ru