32188-59-3Relevant academic research and scientific papers
Copper-catalyzed selective syntheses of Markovnikov-type hydrothiolation products and thioacetals by the reactions of thiols with alkenes bearing heteroatoms
Xi, Hui,Ma, Enlu,Li, Zhiping
, p. 4111 - 4116 (2016/07/06)
Catalyst-controlled divergent reactions of thiophenols with alkenes bearing heteroatoms have been developed. Markovnikov-type hydrothiolation products and thioacetals were synthesized selectively by switching copper catalysts.
The sulfohaloform reaction revisited and revised
Baum, James Clayton,Hardstaff, William Rayne,Langler, Richard Francis,Makkinje, Anthony
, p. 1687 - 1691 (2007/10/02)
A study of the aqueous chlorinolyses of a series of benzylic dithioacetals along with related α-chlorobenzylic sulfides is reported.These results require a modification of our previously proposed sulfohaloform reaction, so that thionium ion intermediates which have at least one alkyl group on sp2 carbon follow a different pathway.
