321918-24-5Relevant academic research and scientific papers
Facile preparation of hexahydropyrrolo[3,2-e][1,4]diazepine-2,5-diones and tetrahydrofuro[1H][3,2-e][1,4]diazepine-2,5-diones by rearrangements of cyclopropylketimines and cyclopropylketones
Funke, Christian,Es-Sayed, Mazen,De Meijere, Armin
, p. 4249 - 4251 (2007/10/03)
(equation presented) Chlorolactames 2a-f reacted with sodium azide to give the cyclopropylketimines 3a-f (75-89%), and acid hydrolysis of 3c,d yielded the cyclopropylketones 6c,d (61-67%). Compounds 3a-f and 6c,d were transformed by heating (170-240°C, su
