3225-31-8Relevant academic research and scientific papers
FTIR and computational studies of gas-phase hydrogen atom abstraction kinetics by t-butoxy radical
Li, Shuping,Fan, Wai Yip
, p. 276 - 280 (2007/10/03)
By using Fourier-Transform Infrared (FTIR) absorption spectroscopy, rate coefficients in the range of 10-16 to 10-14 cm3 molecule-1 s-1 have been determined for the hydrogen atom abstraction reactions of several substrates including halogenated organic compounds and amines by t-butoxy radical generated from the uv photolysis of t-butyl nitrite in the gas phase. Arrhenius parameters for selected reactions have been measured in the temperature range 299-318 K. Transition states and activation barriers for such reactions have been computed with the help of Gaussian 03 software and found to match very well with the experimental values.
Homolytic decomposition of tertiary organochromium(III) complexes and evidence for their decomposition via reactions with aliphatic free radicals. A pulse radiolysis study
Mulac, William A.,Cohen, Haim,Meyerstein, Dan
, p. 4016 - 4020 (2008/10/08)
The rates of homolytic decomposition of Cr-C(CH3)2OH2+-, Cr-C(CH3)2CO2H2+, and Cr-C(CH3)2CN2+ are 0.15 s-1, 4 s-1, and 104 -6 s-1, respectively. The reaction of some aliphatic free radicals,·R with CrIII-R complexes is very fast, K3 ≥ 108 M-1 S-1. The rate of reaction of Cr2+(aq) with H2O2 is k16 = (3.7 ±0.7) × 104 M-1 s-1 in good accord with the literature value. These results are discussed in detail.
