32264-86-1Relevant articles and documents
Preparation of multisubstituted allenes from allylsilanes
Ogasawara, Masamichi,Ge, Yonghui,Uetake, Koichi,Fan, Liyan,Takahashi, Tamotsu
, p. 3871 - 3876 (2007/10/03)
A three-step route of converting allylsilanes to functionalized allenes was developed. Thermal decomposition of 1,1-dibromo-2-(silylmethyl)cyclopropanes, which were quantitatively prepared by treatment of allylsilane derivatives with CHBr3/KOs
THERMOLYSIS OF ALKYL-SUBSTITUTED 1,1-DIBROMO-2-PHENYLCYCLOPROPANES
Molchanov, A. P.,Kostikov, R. R.
, p. 2272 - 2275 (2007/10/02)
When alkyl-substituted gem-dibromophenylcyclopropanes are heated at 170-200 deg C under vacuum the three-membered ring is opened, and hydrogen bromide is released.The substituted 1,3-dienes are formed.