32276-00-9

Basic information

• Product Name: S,S-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate
• Synonyms: S,S-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate;Dithiocarbonic acid S,S-bis(1-phenyl-1H-tetrazol-5-yl) ester
• CAS NO: 32276-00-9
• Molecular Formula: C₁₅H₁₀N₈OS₂
• Molecular Weight: 382.4229
• EINECS: 250-976-9
• Mol File: 32276-00-9.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 652.7°Cat760mmHg
• Flash Point: 348.5°C
• Appearance: /
• Density: 1.61g/cm³
• Vapor Pressure: 6.47E-17mmHg at 25°C
• Refractive Index: 1.835
• CAS DataBase Reference: S,S-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate(CAS DataBase Reference)
• NIST Chemistry Reference: S,S-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate(32276-00-9)
• EPA Substance Registry System: S,S-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate(32276-00-9)

Safety Data

• Hazardous Substances Data: 32276-00-9(Hazardous Substances Data)

Usage

General Description

S,S-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate is a chemical compound with the molecular formula C14H10N8S2. It is used as a reagent in organic synthesis and is commonly employed as a source of tetrazolylthiolate ligands. S,S-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate contains two tetrazole groups, which are five-membered aromatic ring structures containing four nitrogen atoms and one carbon atom. The dithiocarbonate group consists of two carbonyl groups attached to a central sulfur atom. S,S-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate is a versatile chemical reagent with potential applications in coordination chemistry, medicinal chemistry, and materials science.

InChI:InChI=1/C15H10N8OS2/c24-15(25-13-16-18-20-22(13)11-7-3-1-4-8-11)26-14-17-19-21-23(14)12-9-5-2-6-10-12/h1-10H

Upstream product

• 86-93-1 1-phenyl-1H-tetrazole-5-thiol 
• 503-38-8 trichloromethyl chloroformate 
• 86-93-1 1-Phenyl-1H-tetrazole-5-thiol 
• 52427-97-1 trichloromethyl chloroformate 

Downstream Products

• 119815-08-6 5-[(2-furanylmethyl)thio]-1-phenyl-1H-tetrazole 
• 132118-27-5 3-furylmethyl 1-phenyl-1H-tetrazol-5-yl sulfide 
• 118641-54-6 1-phenyl-5-(3-pyridinylmethylthio)-1H-tetrazole 
• 132118-26-4 5-(2-butenylthio)-1-phenyl-1H-tetrazole 
• 119784-90-6 5-(1-methyl-2-propenylthio)-1-phenyl-1H-tetrazole 
• 119793-71-4 5-(1,5-dimethyl-1-vinyl-4-hexenylthio)-1-phenyl-1H-tetrazole 
• 122322-97-8 5-(3,7-dimethyl-2,6-octadienylthio)-1-phenyl-1H-tetrazole 
• 119784-88-2 1-phenyl-5-<(2E,6E)-3,7,11-trimethyl-2,6,10-dodecatrienylthio>-1H-tetrazole 
• 53918-41-5 1-phenyl-5-(prop-2-yn-1-ylsulfanyl)-1H-tetrazole 
• 59-49-4 2-Benzoxazolinone 
• 86-93-1 1-Phenyl-1H-tetrazole-5-thiol 
• 934-34-9 2(3H)-Benzothiazolone 
• 1485-70-7 N-benzylbenzamide 
• 119784-85-9 1-phenyl-5-[[(2E)-3-phenyl-2-propen-1-yl]thio]-1H-tetrazole 

Relevant articles and documents

A mild method for the protection of alcohols using a para-methoxybenzylthio tetrazole (PMB-ST) under dual acid-base activation

With a view to expand the repertoire of chemoselective methods applicable to sensitive and multifunctional substrates, the p-methoxybenzylation of alcohols under essentially neutral conditions is reported. This was achieved by the silver triflate (AgOTf) activation of 5-(p-methoxybenzylthio)-1-phenyl-1H-tetrazole (PMB-ST) in the presence of 2,6-di-tert-butyl-4-methylpyridine (DTBMP).

S,S'-Bis(1-phenyl-1H-tetrazol-5-yl) Dithiocarbonate: A New Esterification Reagent

S,S'-Bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate is a useful reagent for the esterification of carboxylic acids with alcohols, including lactonization.The reagent is conveniently prepared in good yield from 1-phenyl-5-thioxo-4,5-dihydro-1H-tetrazole and trichloromethyl chloroformate (trichloromethyl carbonochloridate) in ethyl acetate in the presence of triethylamine.Its structure was confirmed by (13)C-NMR spectrometry and single-crystal X-ray analysis.