32329-21-8

Basic information

• Product Name: Germylene, chlorophenyl-
• CAS NO: 32329-21-8
• Molecular Formula: C6H5ClGe
• Molecular Weight: 185.149
• Mol File: 32329-21-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Germylene, chlorophenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Germylene, chlorophenyl-(32329-21-8)
• EPA Substance Registry System: Germylene, chlorophenyl-(32329-21-8)

Safety Data

• Hazardous Substances Data: 32329-21-8(Hazardous Substances Data)

Upstream product

• 623-73-4 diazoacetic acid ethyl ester 
• 7366-24-7 phenyldichlorogermane 

Downstream Products

• 74621-46-8 (C₆H₅)GeCHClCOOC₂H₅ 
• 58276-70-3 C₆H₅ClGe(SCH₃)2 
• 32284-95-0 1,2-diphenyltetraethyldigermane 
• 79301-96-5 C₆H₅(C₂H₅)2GeCl 
• 79301-95-4 (C₆H₅)(CH₃CH₂)GeCl₂ 
• 79301-90-9 phenyldiethylgermane 
• 57539-73-8 Phenylethylgerman 
• 1613-66-7 dichlorodiphenylgermane 
• 79301-91-0 (C₆H₅)(CH₃(CH₂)3)GeH₂ 
• 57539-72-7 Phenyldibutylgerman 
• 79301-92-1 (C₆H₅)3Ge(Ge(C₆H₅)CH₃)Ge(C₆H₅)3 
• 79301-97-6 (C₆H₅)3Ge(Ge(CH₃)(C₆H₅))2Ge(C₆H₅)3 
• 2817-44-9 methyltriphenylgermane 
• 74656-34-1 C₆H₅(Cl)GeO 

Relevant articles and documents

ASSISTANCE NUCLEOPHILE DANS DES REACTIONS D'ORGANO-HALOGENO- ET -HALOGENO-HYDROGERMANES: GERMYLANIONS, GERMYLENES, DERIVES FONCTIONNELS DU GERMANIUM

Substitution reactions of halogermanes under nucleophilic assistance of tertiary amines or diazo derivatives leading readily to various functional derivatives of germanium have been carried out.Dehydrohalogenation of acidic halohydrogemanes under nucleophilic assistance is a useful way to divalent species, and the germylenes formed are stabilized by complexation with the nucleophilic agent.The reactions proceed via intermediate halogermylanions which lead to the formation of more stable germylenes.The transient halogemylanions have been characterized by means of their nuclophilic additions to carbonyl derivatives.Nucleophilic substitutions of halogermanes using these germylanions lead to the formation of polygermanes.