32347-01-6Relevant academic research and scientific papers
Cobalt-catalysed synthesis of highly substituted styrene derivatives via arylzincation of alkynes
Corpet, Martin,Gosmini, Corinne
, p. 11561 - 11563,3 (2012/12/12)
A new two-step procedure was developed by carbozincation of internal and terminal alkynes to synthesise highly functionalised vinylzinc bromides. Various tri and tetrasubstituted alkenes were prepared in moderate to good yields under mild reaction conditions in a stereo-selective manner. This methodology represents an interesting alternative to previously known methods. This journal is
Regio- and stereoselective hydrostannation of allenes using dibutyliodotin hydride (Bu2SnIH) and successive coupling with aromatic halides
Hayashi, Naoki,Kusano, Kazunao,Sekizawa, Shingo,Shibata, Ikuya,Yasuda, Makoto,Baba, Akio
, p. 4913 - 4915 (2008/09/18)
Regio- and stereoselective hydrostannation of allenes by using di-n-butyliodotin hydride (Bu2SnIH) was accomplished to give α,β-disubstituted vinyltins, which induced the synthesis of multi-substituted alkenes in a one-pot procedure. The Royal Society of Chemistry.
