32349-49-8

Upstream product

• 104-94-9 4-methoxy-aniline 
• 134-81-6 benzil 
• 783-08-4 [4-(benzylideneamino)phenyl]methanol 
• 2054-16-2 <2-Phenyl-glyoxylsaeurenitril>-<4-methoxy-phenylimin> 
• 10349-38-9 p-methoxyphenylisonitrile 
• 603-33-8 triphenylbismuthane 
• 5470-34-8 4-methoxyformanilide 

Downstream Products

• 170209-09-3 (1R,2R)-1,2-N,N'-bis(4-methoxyphenylamino)-1,2-diphenylethane 
• 134-81-6 benzil 
• 1051966-37-0 C₂₉H₂₅N₂O₂⁽¹⁺⁾*Cl^(1-) 
• 142160-42-7 (((C₆H₅)2C₂N₂(C₆H₄OCH₃)2)Mn)2(C₄H₈O)2 
• 143744-93-8 1,4-bis(4-methoxyphenyl)-2,3-diphenyl-1,4-diaza-1,3-butadiene*ZrCl₄ 
• 1554769-97-9 [Zn(p-anisidine)(1,10-phenanthroline)₂] 
• 1554769-96-8 [Ni(p-anisidine)(1,10-phenanthroline)₂] 
• 1554769-95-7 [Cu(p-anisidine)(1,10-phenanthroline)₂] 

Relevant academic research and scientific papers

Ruthenium-Catalyzed Dehydrogenation Through an Intermolecular Hydrogen Atom Transfer Mechanism

The direct dehydrogenation of alkanes is among the most efficient ways to access valuable alkene products. Although several catalysts have been designed to promote this transformation, they have unfortunately found limited applications in fine chemical synthesis. Here, we report a conceptually novel strategy for the catalytic, intermolecular dehydrogenation of alkanes using a ruthenium catalyst. The combination of a redox-active ligand and a sterically hindered aryl radical intermediate has unleashed this novel strategy. Importantly, mechanistic investigations have been performed to provide a conceptual framework for the further development of this new catalytic dehydrogenation system.

Palladium-Catalyzed Synthesis of α-Diimines from Triarylbismuthines and Isocyanides

In this study, we report a highly selective coupling reaction between triarylbismuthines and isocyanides using palladium diacetate as the catalyst, affording α-diimines, with the formation of three C-C bonds. Among several aryl sources (Ar-YLn: Y = B, Sn, Pb, Sb, Bi, I), only triarylbismuthines successfully undergo coupling with isocyanides to selectively afford α-diimines. The coupling reaction exhibits the advantages of high atom economy and convenient operation, with no need for any additive.

Bio active mixed ligand complexes of Cu(II), Ni(II) and Zn(II): Synthesis, spectral, XRD, DNA binding and cleavage properties

The paper presents the synthesis of complex combinations of Cu(II), Zn(II) and Ni(II) with Schiff bases obtained by the condensation reaction of diphenylglyoxal with 1-amino-4-nitrobenzene (L1)/1-amino-4- chlorobenzene (L2)/p-anisidi

Stereoselective synthesis of cis- and trans-4-acyl-β-lactams from vicinal diketones and ketoaldehydes

4-Acyl-β-lactams are important synthetic intermediates in both pharmaceutical and organic chemistry. Cis- and trans-4-acyl-β-lactams were synthesized stereoselectively from vicinal diketones via the formation of bulky and less bulky diimines as key interm

Electronically tunable N-heterocyclic carbene ligands: 1,3-diaryl vs. 4,5-diaryl substitution

The catalytic activity of iridium-mediated transfer hydrogenation is readily tuned by electronic variation of the ligated tetraaryl-N-heterocyclic carbene and the installation of electron donating groups on the N-aryl substituents is more important than o

DNA-interaction and in vitro antimicrobial studies of some mixed-ligand complexes of cobalt(II) with fluoroquinolone antibacterial agent ciprofloxacin and some neutral bidentate ligands

Six new mixed-ligand complexes of Co(II) with ciprofloxacin (Cip) and neutral bidentate ligands have been synthesized and characterized. Binding and cleavage of DNA with the complex were investigated using spectroscopic method, viscosity measurements and gel electrophoresis techniques. Antibacterial activity has been assayed against two Gram(-ve) and three Gram(+ve) microorganisms using the doubling dilution technique.

Synthesis of electronically diverse tetraarylimidazolylidene carbenes via catalytic aldimine coupling

(Chemical Equation Presented) A new method for synthesizing symmetrical N-heterocyclic imidazolium salts is described. Catalytic coupling of aldimines with cyanide followed by oxidation gives α-diketimines, which can then be cyclized with formaldehyde in

Microwave-assisted efficient synthesis of diimines in dry media using silica gel supported sodium hydrogen sulfate as reusable solid support

A simple and efficient method for synthesis of diimines using silica gel supported sodium hydrogen sulfate as reusable solid support in solvent-free conditions under microwave irradiation is described.

A novel decyanogenative coupling of α-cyanoimines mediated by samarium. A facile route to α-diketimines

Conversion of α-cyanoimines 1 into α-diketimines 2 has been achieved successfully by using samarium diiodide in dry tetrahydrofuran in high yields without formation of anilinoanil 3, 1,2-diamines 4 or anilides 5.

Formation of benzil diimines by microwave-assisted reaction of benzil with aromatic amines on alumina surface without solvent

The microwave-assisted solvent-free reaction of benzil with aromatic amines (in 1 : 2 molar ratio) on an alumina surface for 4 min affords benzil diimines (1,2,3,4-tetraaryl-1,4-diaza-1,3-butadienes).