32382-67-5

Upstream product

• 37072-63-2 N-(2-methylphenyl)oxazolidin-2-one 
• 124-41-4 sodium methylate 
• 95-53-4 o-toluidine 

Downstream Products

• 70040-55-0 (2-Methoxy-ethyl)-o-tolyl-carbamic acid 3-methylsulfanylcarbonylamino-phenyl ester 
• 70040-34-5 C₁₉H₂₂N₂O₅ 
• 70040-41-4 (2-Methoxy-ethyl)-o-tolyl-carbamic acid 3-ethylsulfanylcarbonylamino-phenyl ester 
• 103867-36-3 3-Cyclohexyl-N-(2-methoxy-ethyl)-2-methyl-N-o-tolyl-propionamide 
• 103867-29-4 N-(o-tolyl)-N-(2-methoxyethyl)-3-cyclohexylpropionamide 
• 50563-41-2 N-chloroacetyl-N-(2-methoxyethyl)-2-methylaniline 
• 70040-40-3 C₂₀H₂₄N₂O₅ 

Relevant academic research and scientific papers

ANOMALOUS RING OPENING OF N-ARYL-2-OXAZOLIDINONES BY ANHYDROUS ALKOXIDE:A CONVENIENT PREPARATION OF N-(ALKOXYETHYL)-2,6-DISUBSTITUTED ANILINES

N-(2-Alkoxyethyl)anilines may be prepared by acylation of an N-unsubstituted aniline with 2-chloroethyl chloroformate, ring closure to oxazolidinone, ring opening with alkoxide under anhydrous conditions to a carbamic acid salt, and decarboxylation.This unexpected mode of ring opening is especially useful in the preparation of N-(2-alkoxyethyl)-2,6-disubstituted anilines.

Process for the preparation of 2,6-dialkyl-N-alkylanilines

A process for the preparation of 2,6-dialkyl-N-alkylanilines is disclosed, which process comprises the reaction of a 2,6-dialkylaniline with an alkanol at 200° to 350° C. in the presence of a copper-containing catalyst which contains 0.05 to 10% by weight of palladium or platinum.