32405-87-1Relevant academic research and scientific papers
Trichlorocyanuric acid: An efficient reagent for one-pot synthesis of Ptychodiscus brevis (PB-1) toxin and its derivatives
Gupta, Arvind K.,Acharya, Jyotiranjan,Dubey, Devendra K.,Kaushik, Mahabir P.
, p. 29 - 33 (2008/02/02)
Trichlorocyanuric acid is an efficient regent for simple and one-pot synthesis of dialkyl, N-cycloctylphosphoraamidates (PB-1) and its various derivatives in excellent yields. The procedure is operationally simple and involves the reaction of various dialkylphosphites with trichloroisocyanuric acid in acetonitrile and subsequent treatment with amines in presence KF-celite to give PB-1 and derivatives.
SOLVOLYSIS OF DIPHENYL AMIDOPHOSPHATES IN AQUEOUS ALCOHOLIC MEDIA
Kasparek, Frantisek,Mollin, Jiri
, p. 386 - 396 (2007/10/02)
Influence of substituent on the reaction rate of the alkali-catalyzed solvolysis of the studied compounds set has been followed.The activation entropy has also been determined.The reaction products have been identified, and their concentration ratio has been determined.The reaction selectivity is mostly influenced by sterical effects in the substrate molecule.The results obtained agree with the SN2 mechanism.
