324745-59-7Relevant academic research and scientific papers
Palladium catalysed cross-coupling of (fluoroarene)tricarbonylchromium(0) complexes
Widdowson, David A.,Wilhelm, Rene
, p. 2211 - 2212 (1999)
Fluoroarenetricarbonylchromium(0) complexes were found to undergo Suzuki reactions with arylboronic acids to form biaryltricarbonylchromium(0) complexes in the presence of trimethylphosphine/palladium dibenzylideneacetone and caesium carbonate or caesium
Palladium catalysed cross-coupling of (fluoroarene)tricarbonyl-chromium(o) complexes
Wilhelm, Rene,Widdowson, David A.
, p. 3808 - 3813 (2007/10/03)
(Fluoroarene)tricarbonylchromium(o) complexes were found to undergo Suzuki and Stille cross-coupling reactions to form functionalised biaryl and styrene complexes in up to 87 and 52% yields, respectively. The Suzuki reactions were optimal with dipalladium tris(dibenzylideneacetone)-trimethylphosphine-caesium carbonate in DME at reflux. The Stille reactions were optimal with dipalladium tris(dibenzylideneacetone)-trimethylphosphine-caesium fluoride in DME at reflux and neither was adversely affected by a methoxy group on the complexed ring. The Suzuki reaction tolerated a chloro group on the arylboronic acid ring but not a bromo group. The Royal Society of Chemistry 2000.
