32490-47-4

Upstream product

• 15318-33-9 chlorocarbonylbis(triphenylphosphine)rhodium(I) 
• 75-05-8 acetonitrile 
• 178435-03-5 [trans-Rh(CO)(PPh₃)2(NCCH₃)O₂](+)ClO₄(-) 
• 32354-26-0 Rh(ClO₄)(CO)(PPh₃)2 

Downstream Products

• 82108-62-1 {Rh(OC(O)C₆H₄Cl)(CO)(P(C₆H₅)3)2} 
• 32354-34-0 trans-Rh(PPh₃)2(CO)(acetate) 

Relevant academic research and scientific papers

Reactions of Singlet Oxygen with Organometallic Compounds. 4. Photooxidation of Cationic Iridium(I) and Rhodium(I) Complexes with Weakly Bonded Ligands

Cationic complexes of the type [M(CO)S(PPh3)2]+ (M = Ir, Rh; S = CH3CN) react with singlet oxygen to form the corresponding peroxo complexes [M(CO)S(PPh3)2(O2)]+. The solvent molecule remains coordinated to the metal in the oxygen adducts. The novel cationic iridium-peroxo complex is stable at room temperature, while the rhodium-peroxo complex is only stable below 0 °C. Rate constants for physical and chemical interaction of the complexes with singlet oxygen are somewhat smaller than those for related neutral complexes. Upon addition of alkenes (tetramethylethylene or 1-octene) to the peroxo complexes, neither oxidation of the olefins nor substitution of the acetonitrile ligand was observed. 1-Octene was isomerized to give mostly 2- and 3-octene by the cationic rhodium(I) complex. A cationic indium complex which already possesses a coordinated diene ligand ([Ir(COD)-(PPh3)2]+) did not react with or quench singlet oxygen.

Reactions involving Transition Metals. Part 15. Reactions of Alkyl an Acyl-peroxy-anions with (1+) (M= Ir or Rh)

The title compounds react with peroxycarboxylic acids RCO3H in the presence of NEt3 to give the compounds (L = PPh3), which, with MeI, give and (R = C6H4Cl-m, Ph, or Me).Reaction between NaO2COR' (R' = C6H4Cl-m) and (1+) affords an inseparable mixture of , , and ; under similar conditions the rhodium analogue gives a mixture of and .Reactions between NaO2But and either (1+) or give only .