32501-16-9

Upstream product

• 13659-87-5 (+)-2-acetyl-6,6-dimethylbicyclo<3.1.0>hex-2-ene 
• 32543-59-2 2-((1R,3S)-2,2-dimethyl-3-(2-oxopropyl)cyclopropyl)acetaldehyde 
• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 26946-56-5 2,2-dimethyl-3-(2-oxopropyl)cyclopropane acetaldehyde 
• 1067-74-9 Methyl diethylphosphonoacetate 

Downstream Products

• 49827-44-3 dimethyl 2,2-dimethylsuccinate 
• 56973-88-7 1-(3,3-dimethyl-cyclohexa-1,4-dien-1-yl)-pent-4-en-1-one 
• 56973-86-5 1-(3,3-dimethyl-cyclohex-4-en-1-yl)-pent-4-en-1-one 
• 106672-99-5 Toluene-4-sulfonic acid 2-(5,5-dimethyl-cyclohex-3-enyl)-ethyl ester 
• 106673-13-6 Toluene-4-sulfonic acid 5,5-dimethyl-cyclohex-3-enylmethyl ester 
• 106673-08-9 5-(5,5-Dimethylcyclohex-3-en-1-yl)pentan-2-one 
• 106673-15-8 (5,5-Dimethylcyclohex-3-en-1-yl) acetic acid 
• 106673-25-0 (5,5-Dimethylcyclohex-3-en-1-yl)acetaldehyde 
• 106673-02-3 5-(2-Bromo-ethyl)-3,3-dimethyl-cyclohexene 
• 106673-23-8 2-(5,5-Dimethylcyclohex-3-en-1-yl)ethanol 

Relevant academic research and scientific papers

Synthesis of Juvenoids with the 5,5-Dimethylcyclohex-3-en-1-yl System

A new group of juvenoids with the 5,5-dimethylcyclohex-3-ene system was obtained by a multi-step synthesis starting from (+)-3-carene (1).Esters 15, 16 and 18 were synthesized by the Wadsworth-Emmons reaction of ketone 14 or aldehyde 17 with appropriate p

STEREOCHEMISTRY OF BICYCLOHEXANE DERIVATIVES. PART XIV. WITTIG REACTIONS. REARRANGMENENT OF BICYCLOHEXANE SYSTEM TO CYCLOHEXANE SYSTEM

Modified Wittig reactions of (+)-2-acetyl-6,6-dimethylbicyclohex-2-ene (1) and its epoxidation product 2 were carried out.Homogeneous products, nitrile 3 and ester 4 with the retained bicyclic system, were obtained from 2.On the other hand, ketone