32501-91-0

Upstream product

• 1142-19-4 4,4'-dichlorodiphenyl disulfide 
• 1066-54-2 trimethylsilylacetylene 
• 98-60-2 4-chlorobenzenesulfonyl chloride 
• 32598-27-9 (4-chlorobenzenesulfonylethynyl)trimethylsilane 

Downstream Products

• 99908-18-6 (1S,2R,4R)-1-[(Z)-2-(4-Chloro-benzenesulfonyl)-vinylsulfanylmethyl]-7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol 
• 42175-12-2 butyl (E)-4-chlorocinnamate 
• 104012-55-7 (1S,2R,4R)-1-[(Z)-2-(4-Chloro-benzenesulfonyl)-ethenesulfinylmethyl]-7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol 
• 103953-52-2 (1S,4R,6R,8R)-4-(4-Chloro-benzenesulfonylmethyl)-11,11-dimethyl-5-oxa-3-thia-tricyclo[6.2.1.0^1,6]undecane 3-oxide 
• 103953-53-3 (1S,4R,6R,8R)-4-(4-Chloro-benzenesulfonylmethyl)-11,11-dimethyl-5-oxa-3-thia-tricyclo[6.2.1.0^1,6]undecane 3,3-dioxide 
• 103953-46-4 (1S,2R,4R)-1-[(E)-2-(4-Chloro-benzenesulfonyl)-vinylsulfanylmethyl]-7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol 
• 103953-48-6 (1S,4S,6R,8R)-4-(4-Chloro-benzenesulfonylmethyl)-11,11-dimethyl-5-oxa-3-thia-tricyclo[6.2.1.0^1,6]undecane 
• 1033235-31-2 N-benzyl-3-(p-chlorobenzenesulfonyl)azacyclotrideca-2,5-diene 
• 1033235-32-3 N-benzyl-3-(p-chlorobenzenesulfonyl)azacyclotetradeca-2,5-diene 
• 1239144-72-9 1-benzenesulfonyl-2-[1,4-dibenzyl-6-(p-chlorobenzenesulfonyl)-2,3,4,5-tetrahydro-1H-1,4-diazepin-5-yl]-1H-indole 
• 99946-18-6 (1S,2R,4R)-1-[(S)-(Z)-2-(4-Chloro-benzenesulfonyl)-ethenesulfinylmethyl]-7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol 
• 99894-25-4 (1S,2R,4R)-1-[(R)-(1S,2R,3S,4R)-3-(4-Chloro-benzenesulfonyl)-bicyclo[2.2.1]hept-5-ene-2-sulfinylmethyl]-7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol 

Relevant academic research and scientific papers

Oxidative addition of Pd(0) to Ar-SO2R bonds: Heck-type reactions of sulfones

Phenyl vinyl sulfones and sulfoxides react with Pd(OAc)2 to form styryl sulfoxides and sulfones according to the first Mizoroki-Heck reaction reported for these thio derivatives. Only sulfones are able to react by using catalytic amounts of Pd