32534-81-9

Basic information

• Product Name: Pentabromodiphenyl ether
• Synonyms: PENTABROMODIPHENYL ETHER;PENTABROMOPHENYL ETHER;diphenyl ether, pentabromo derivative;Benzene, 1,1-oxybis-, pentabromo deriv.;pentabromodiphenylether (technical mixture);PENTABROMOBIPHENYLETHER;PBDECONGENER99;PENTA-BROMINATEDDIPHENYLETHER
• CAS NO: 32534-81-9
• Molecular Formula: C12H5Br5O
• Molecular Weight: 564.69
• EINECS: 251-084-2
• Product Categories: Organics
• Mol File: 32534-81-9.mol
• Article Data: 0

Chemical Properties

• Boiling Point: 430.768°C at 760 mmHg
• Flash Point: 178.529°C
• Appearance: /
• Density: 2.344g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.681
• Water Solubility: Insoluble (
• Stability: Incompatible with strong oxidizing agents.
• CAS DataBase Reference: Pentabromodiphenyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: Pentabromodiphenyl ether(32534-81-9)
• EPA Substance Registry System: Pentabromodiphenyl ether(32534-81-9)

Safety Data

• Hazard Codes: Xn,N
• Statements: 48/21/22-50/53-64
• Safety Statements: 36/37-45-60-61
• RIDADR: 3152
• HazardClass: 9
• PackingGroup: II
• Hazardous Substances Data: 32534-81-9(Hazardous Substances Data)

Usage

Description

Pentabromodiphenyl ether (PBDE-99) is an amber coloured solid, and insoluble in water. It is a halogenated organic compound and is very unreactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group are incompatible with strong oxidising and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. 2,2′,4,4′,5-Pentabromodiphenyl ether (PBDE-99) was in use as a component of many commonly used flame retardants, including DE-71, Bromkal G1, and other popular mixtures. DE-71 was sold as a flame retardant for unsaturated polyester, rigid and flexible polyurethane foams, epoxies, laminates, adhesives, and coatings. The PBDEs are used in paint, high-impact plastic, foam, and textiles, as well as in electronic, building, automotive, furniture, and household plastic products. The U.S. manufacturers and the EU have banned the use of PBDE since 2004.

Chemical Properties

amber solid

General Description

Amber solid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Simple aromatic halogenated organic compounds are very unreactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

Fire Hazard

Flash point data for Pentabromodiphenyl ether are not available, but Pentabromodiphenyl ether is probably combustible.

Safety Profile

A poison by ingestion. Moderately toxic by inhalation. Low toxicity by skin contact. A moderate skin irritant. When heated to decomposition it emits toxic vapors of Brí

InChI:InChI=1/C12H5Br5O/c13-7-8(14)10(16)12(11(17)9(7)15)18-6-4-2-1-3-5-6/h1-5H