325465-65-4

Upstream product

• 106-96-7 propargyl bromide 
• 139-85-5 3,4-dihydroxybenzaldehyde 

Downstream Products

• 1616487-84-3 (E)-1-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-4-(3,4-bisprop-1’-oxo-2’-yne phenyl)-but-3-ene-2-one 
• 1616487-86-5 (E)-1-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-4-{3,4-bis[1'-(dodecyl)-4'-hydroxymethylenetriazolo]phenyl}but-3-ene-2-one 
• 1616487-85-4 (E)-1-(4,6-O-butylidene-β-D-glucopyranosyl)-4-{3,4-bis[1'-(dodecyl)-4'-hydroxymethylenetriazolo]phenyl}but-3-ene-2-one 
• 1616487-81-0 (E)-1-(4,6-O-butylidene-β-D-glucopyranosyl)-4-(3,4-bisprop-1’-oxo-2’-yne phenyl)-but-3-ene-2-one 

Relevant academic research and scientific papers

Novel fluorescent sensor for silver (I) based on the 3,4-bis-triazole Bodipy via dual-click chemistry

This investigation paper relates with a novel dual-Bodipy derivative obtained by using ‘click’ chemistry. The synthesized compounds were characterized by some techniques as 1H NMR, 13C NMR, 11B-NMR, 19F NMR, FT-

Reaction-based fluorescent silk probes with high sensitivity and selectivity to Hg2+and Ag+ions

The detection and removal of heavy metals in the environment is urgent and meaningful. In this work, two types of fluorescent functionalized silksOSPandASPhave been prepared using worm silk as the substrate. These fluorescent silk probes exhibit an obvious fluorescence quenching effect in the presence of Hg2+or Ag+, enabling silk to specifically detect Hg2+or Ag+. An obvious color response occurs under visible light, from yellow to brown or gray, thereby realizing dual-channel identification of fluorescence and colorimetry. In addition, its sensing mechanism has been studied, and it is found that the probe reacts with metal ions as a reactive response. Compared with the fluorescent probes bearing one C-C/C-C bond, the probes with two terminal C-C/C-C bonds are more sensitive. And the excellent recognition ability can make the limit of detection as low as 0.25 μM. This indicates that silk fluorescent probes can be used to detect Hg2+and/or Ag+

Facile Synthesis of Mono- and Polytopic β -Cyclodextrin Aromatic Aldehydes by Click Chemistry

The first examples of mono-, di-, and trimeric β-cyclodextrin aromatic aldehyde derivatives 5, 10, and 11 were designed and conveniently synthesized by using the CuI-catalyzed azide-alkyne cycloaddition reaction of mono-6-azido-cyclodextrin (CD

Novel columnar liquid crystalline oligomers: Triphenylene tetramers with rigid aromatic Schiff-bases and hydrogen-bonding spacers via click chemistry

Three novel triphenylene tetramers with triazole bridges, rigid aromatic Schiff-bases and hydrogen-bonding spacers were designed and synthesized in yield of 73–78%. Their structures were confirmed by IR, NMR and MS. Their mesomorphic properties were studi

FRET-capable supramolecular polymers based on a BODIPY-bridged pillar[5]arene dimer with BODIPY guests for mimicking the light-harvesting system of natural photosynthesis

AA/BB-type and A2/B3-type FRET-capable supramolecular polymers based on a BODIPY-bridged pillar[5]arene dimer and two BODIPY derivative guests have been successfully constructed and their application in mimicking the light-harvesting

Novel β-cyclodextrin-[60]fullerene conjugates based on huisgen [2+3] cycloaddition: Synthesis and dyes complexation properties

By using β-cyclodextrin aromatic aldehyde derivatives 5 and 6 as starting materials, the novel β-cyclodextrin-[ 60]fullerene conjugate 7 and bis- β-cyclodextrin-[ 60]fullerene conjugate 8 were designed and conveniently synthesized via the Huisgen [2+3] cy

Dual core clickate fluorophores for selective recognition of Cu2+ and Ni2+ along with live cell imaging

Triazole based four unique fluorophores (P1, P2, P3, and P4) have been synthesized, which exhibited excellent Aggregation Induced emission (AIE) effect in ACN/H2O (v/v = 1:1). It was observed that two specific cavities were developed for select

Application of stimuli-responsive FRET behavior toward cyanide detection in a photo-switchable [2]pseudorotaxane polymer containing the BODIPY donor and the merocyanine acceptor

We have developed a supramolecular (close form) [2]pseudorotaxane polymer containing the green-emissive (λem= 523 nm) BODIPY-based pillar[5]arene host and the non-emissive spiropyran (SP)-based cyano guest (close form), which can be converted t

Photolysis of the BODIPY dye activated by pillar[5]arene

Here, a pseudo[3]rotaxane comprising a fluorescent BODIPY derivative and pillar[5]arene was conveniently fabricatedviahost-guest complexation. Importantly, in this system, the efficient photodecomposition of the BODIPY derivative in the presence of pillar

Curcuminoid-BF2 complexes: Synthesis, fluorescence and optimization of BF2 group cleavage

Eight difluoroboron complexes of curcumin derivatives carrying alkyne groups containing substituents have been synthesized following an optimised reaction pathway. The complexes were received in yields up to 98% and high purities. Their properties as fluo