32552-21-9Relevant articles and documents
Synthesis and antifungal activity of 7-methyl-7-hydroxy-2,3-benzo[c]octa-1, 6-olide
Zhao, Jin,Dong, Hong-Bo,Yang, Ming-Yan,Du, Juan,Jiang, Jia-Zheng,Wang, Ming-An
, p. 312 - 317 (2014/02/14)
The racemic 7-methyl-7-hydroxy-2,3-benzo[c]octa-1,6-olide, the analog of natural product (6R)-3,7-dimethyl-7-hydroxy-2-octen-1,6-olide, was totally synthesized using easily available (E)-2-(2-carboxyvinyl)benzoic acid as a raw material in nine-step reacti
Supramolecular control of selectivity in hydroformylation of vinyl arenes: Easy access to valuable β-aldehyde intermediates
Dydio, Pawel,Reek, Joost N. H.
, p. 3878 - 3882 (2013/05/09)
Go against the flow! A rationally designed regioselective hydroformylation catalyst, [Rh/L], in which noncovalent ligand-substrate interactions allow the unprecedented reversal of selectivity from the typical α-aldehyde to the otherwise unfavored product β-aldehyde, is reported. This catalytic system opens up novel and sustainable synthetic pathways to important intermediates for the fine-chemicals industry.
Synthesis of Isomeric Methyl ε-Hydroxycarboxylates
Arth, Christoph,Clemens, Martina,Meise, Werner
, p. 259 - 264 (2007/10/02)
The synthesis of the three isomeric methyl ε-hydroxycarboxylates 3, 6 and 10a in good overall yields is described. - Key Words: Methyl ε-hydroxycarboxylates / Carboxylic acids, ε-hydroxy- / Phenylalkanoic acids, o-(hydroxyalkyl)-