325981-92-8

Basic information

• Product Name: (3R,3aS,7S,7aR)-3-Benzyloxymethyl-7-methyl-hexahydro-isobenzofuran-1-one
• Synonyms: (3R,3aS,7S,7aR)-3-Benzyloxymethyl-7-methyl-hexahydro-isobenzofuran-1-one
• CAS NO: 325981-92-8
• Molecular Weight: 274.36
• Mol File: 325981-92-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3R,3aS,7S,7aR)-3-Benzyloxymethyl-7-methyl-hexahydro-isobenzofuran-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,3aS,7S,7aR)-3-Benzyloxymethyl-7-methyl-hexahydro-isobenzofuran-1-one(325981-92-8)
• EPA Substance Registry System: (3R,3aS,7S,7aR)-3-Benzyloxymethyl-7-methyl-hexahydro-isobenzofuran-1-one(325981-92-8)

Safety Data

• Hazardous Substances Data: 325981-92-8(Hazardous Substances Data)

Upstream product

• 98897-64-4 (E)-6-[(tert-butyldimethylsilyl)oxy]-2-hexen-1-ol 
• 440083-43-2 (2S,3S)-6-(tert-butyldimethylsilyl)oxy-2,3-epoxyhexan-1-ol 
• 100-39-0 benzyl bromide 

Downstream Products

• 325981-97-3 (3R,3aS,7S,7aR)-3-Benzyloxymethyl-7,7a-dimethyl-hexahydro-isobenzofuran-1-one 
• 325982-00-1 (R)-1-((1S,2R,3S)-2-Hydroxymethyl-2,3-dimethyl-cyclohexyl)-ethane-1,2-diol 
• 122518-92-7 (1S,2R,3S)-2-(hydroxymethyl-2,3-dimethylcyclohexyl)methanol 

Relevant articles and documents

Regiocontrol of radical cyclization by Lewis acids. Efficient synthesis of optically active functionalized cyclopentanes and cyclohexanes

(equation presented) Treatment of α-alkylidenelactones 3a-d with Bu3SnH and a catalytic amount of Et3B effected a 5-exo radical cyclization preferentially to provide the corresponding 1 and 2 in a ratio of 70:30 to 100:0. Meanwhile,