326-67-0

Upstream product

• 103-89-9 4-Methylacetanilide 
• 452-80-2 2-fluoro-4-methylaniline 
• 108-24-7 acetic anhydride 
• 75-36-5 acetyl chloride 
• 352-70-5 m-Fluorotoluene 
• 446-34-4 2-fluoro-4-methyl-1-nitrobenzene 

Downstream Products

• 713-11-1 4-acetamido-3-fluorobenzoic acid 
• 449774-77-0 2-fluoro-4-methyl-6-nitroaniline 
• 259860-00-9 2-fluoro-4-methyl-5-nitro-phenylamine 
• 1242553-53-2 5-acetamido-4-fluoro-2-methylbenzene-1-sulfonyl chloride 
• 449774-82-7 (2R,3S,5R)-2-[Bis-(4-methoxy-phenyl)-phenyl-methoxymethyl]-5-(4-fluoro-6-methyl-benzoimidazol-1-yl)-tetrahydro-furan-3-ol 
• 449774-80-5 C₂₉H₂₇FN₂O₅ 
• 449774-78-1 4-fluoro-6-methyl-1H-benzimidazole 
• 168966-55-0 1-fluoro-5-methyl-2,3-diaminobenzene 
• 1242552-48-2 2-(2,2,2-trifluoroethylsulfinyl)-4-(4-oxo-quinazolin-3-yl)-5-fluoro-toluene 
• 1242553-69-0 N-(2-amino-benzoyl)-3-(2,2,2-trifluoroethylsulfanyl)-4-methyl-6-fluoro-aniline 
• 1242553-66-7 N-(2-nitro-benzoyl)-3-(2,2,2-trifluoroethylsulfanyl)-4-methyl-6-fluoro-aniline 
• 1242552-44-8 2-(2,2,2-trifluoroethylsulfanyl)-4-(4-oxo-quinazolin-3-yl)-5-fluoro-toluene 

Relevant academic research and scientific papers

Aryl sulfide containing benzylamine structure and synthesis method and application thereof

The invention belongs to the technical field of pesticides, and particularly relates to aryl sulfide containing a benzylamine structure and a synthesis method and application of the aryl sulfide. Represented by the following compounds: or an agriculturall

NOVEL BENZYLAMIDE COMPOUND, METHOD FOR PRODUCING THE SAME, AND MITICIDE

An object of the present invention is to provide a benzylamide compound or a salt thereof that controls a mite. The present invention provides a benzylamide compound represented by Formula (1): or a salt thereof, wherein R1 represents C1-6 alkyl or C1-6 haloalkyl; R2 and R3 are identical or different and each represent hydrogen, halogen, cyano, nitro, C1-6 alkyl, or the like; R4 represents hydrogen, formyl, C1-6 alkyl, or the like; R5 and R6 are identical or different and each represent hydrogen, halogen, or C1-6 alkyl, or the like; R7, R8, R9, R10, and R11 are identical or different and each 5 represent hydrogen, halogen, or the like; X represents oxygen or sulfur; and n represents an integer of 0 to 2.

NOVEL BENZYLAMIDE COMPOUND, METHOD FOR PRODUCING THE SAME, AND MITICIDE

An object of the present invention is to provide a benzylamide compound or a salt thereof that controls a mite. The present invention provides a benzylamide compound represented by Formula (1): or a salt thereof, wherein R1 represents C1-6 alkyl or C1-6 haloalkyl; R2 and R3 are identical or different and each represent hydrogen, halogen, cyano, nitro, C1-6 alkyl, or the like; R4 represents hydrogen, formyl, C1-6 alkyl, or the like; R5 and R6 are identical or different and each represent hydrogen, halogen, or C1-6 alkyl, or the like; R7, R8, R9, R10, and R11 are identical or different and each represent hydrogen, halogen, or the like; X represents oxygen or sulfur; and n represents an integer of 0 to 2.

NOVEL AMIDE COMPOUND, METHOD FOR PRODUCING THE SAME, AND MITICIDE

An object of the present invention is to provide an amide compound or a salt thereof that controls a mite. The present invention provides an amide compound represented by Formula (1) : or a salt thereof, wherein R1 represents C1-6 alkyl or C1-6 haloalkyl; R2 and R3 are identical or different and each represent hydrogen, halogen, cyano, nitro, C1-6 alkyl, or the like; Q represents Q-1 or Q-2: R4 represents hydrogen, C1-6 alkyl, acetyl or the like; R5 and R6 are identical or different and each represent hydrogen, halogen, or C1-6 alkyl, or the like; HET represents 5- or 6-membered heteroaryl, R7 represents C1-6 alkyl, C1-6 haloalkyl, C3-8 cycloalkyl, C3-8 cycloalkyl C1-6 alkyl, substituted or unsubstituted aryl, substituted or unsubstituted aryl C1-6 alkyl X represents oxygen or sulfur; and n represents an integer of 0 to 2.

Synthesis of 2-methylbenzoxazoles directly from: N -phenylacetamides catalyzed by palladium acetate

A method to synthesize 2-methylbenzoxazoles directly from N-phenylacetamides catalyzed by Pd(OAc)2 in the presence of K2S2O8 and TfOH has been developed. The desired products were obtained in moderate to excellent yields. This approach provides a facile procedure to prepare benzoxazoles with available substrates. It is found that TfOH is the key factor for this cyclization reaction. A plausible mechanism of the reaction is proposed according to the control reactions and the literature.

Amide-assisted radical strategy: Metal-free direct fluorination of arenes in aqueous media

A metal- and initiator-free direct fluorination of arenes with the assistance of an amide group is developed. This reaction proceeded under simple aqueous conditions with good functional group tolerance and ortho-para selectivity, and is highly practical because it could be readily scaled up to a multigram-scale. At this stage, an exclusive mechanism could not be proposed, and several possibilities have been discussed. The possibility of the amide-assisted radical chain mechanism has been supported by experimental and computational investigations as well as a seminal work.

Regioselective and efficient bromination of anilides on water using HBr and Selectfluor

A metal-, additive-, and Br2-free highly regioselective bromination of anilides using HBr and Selectfluor is presented. This reaction proceeded under mild conditions with high efficiency and good functional group tolerance, and water served as the solvent. In general, with substrates bearing no para-substituent, para-mono-bromination occurred exclusively, while ortho-mono-brominated anilides were the only products when para-positions were blocked. The incorporation of a stronger orienting group might result in a reversed regioselectivity, and the reaction was sensitive to steric hindrance.

INSECTICIDAL ACTIVE MIXTURES COMPRISING ARYLQUINAZOLINONE COMPOUNDS

Pesticidal active mixtures comprising arylquinazolinone compounds The present invention relates to pesticidal mixtures comprising as active compounds 1) at least one pesticidal active 3-arylquinazolin-4-one compound I of formula (I) wherein R1, R2, R3, R4, k and n are defined in the description; and 2) at least one active compound II selected from a group M comprising acteylcholine esterase inhibitors, GABA-gated chloride channel antagonists, sodium channel modulators, nicotinic acteylcholine receptor agonists/antagonists, allosteric nicotinic acetylcholine receptor activitaors, chloride channel activators, juvenile hormone mimics, homopteran feeding blockers, mit grow inhibitors, inhibitors of mitochondrial bATP synthase, uncouplers of the oxidative phosphorylation, inhibitors of the chitin biosynthesis, moulting disruptors, ecdyson receptor agonists, octamin receptor agonists, inhibitors of the MET, voltage-dependent sodium channel blockers, inhibitors of the lipid synthesis, ryanodine receptor modulators and other compounds as defined in the description, in synergistically effective amounts. The invention relates further to methods and use of these mixtures for combating and controlling insects, arachnids or nematodes in and on plants, and for protecting such plants being infested with pests, especially also for protecting plant proparagation material, such as seeds.

USE OF PESTICIDAL ACTIVE 3-ARYLQUINAZOLIN-4-ONE DERIVATIVES IN SOIL APPLICATION METHODS

PF72171 60 Abstract Use of pesticidal active 3-arylquinazolin-4-one derivatives in soil application methods The present invention relates to agricultural methods and the use of 3-arylquinazolin-4-5 one derivatives of formula (I) N N O S(O) n R 1 R 3 R 2 (R 4 ) k (I) wherein R1, R2, R3, R4, k and n are defined in the description in soil application methods.10 The compounds of the formula (I) are highly suitable for controlling animal pests such as insects and/or spider mites and/or nematodes by treating the soil/growth substrate by drenching or drip application or dipping or soil injection. 15

AGRICULTURAL MIXTURES COMPRISING ARYLQUINAZOLINONE COMPOUNDS

The present invention relates to pesticidal mixtures comprising as active compounds 1) at least one pesticidal active 3-arylquinazolin-4-one compound I of formula (I): wherein R1, R2, R3, R4, k and n are defined in the description; and 2) at least one fungicidal compounds II selected from azoles, strobilurins, carboxamides, carbamates, heterocyclic and various other compounds as defined in the description, in synergistically effective amounts. The invention relates further to methods and use of these mixtures for combating insects, arachnids or nematodes and harmful fungis in and on plants, and for protecting such plants being infested with pests, especially also for protecting seeds.