326173-43-7

Basic information

• Product Name: 4-thiocyanato-N-phenyl-2,2-iminodiethanol
• Synonyms: 4-thiocyanato-N-phenyl-2,2-iminodiethanol
• CAS NO: 326173-43-7
• Molecular Weight: 220.295
• Mol File: 326173-43-7.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: 4-thiocyanato-N-phenyl-2,2-iminodiethanol(CAS DataBase Reference)
• NIST Chemistry Reference: 4-thiocyanato-N-phenyl-2,2-iminodiethanol(326173-43-7)
• EPA Substance Registry System: 4-thiocyanato-N-phenyl-2,2-iminodiethanol(326173-43-7)

Safety Data

• Hazardous Substances Data: 326173-43-7(Hazardous Substances Data)

Upstream product

• 92-53-5 4-Phenylmorpholine 
• 108-86-1 bromobenzene 
• 540-72-7 sodium thiocyanide 
• 2248-34-2 4-(4-morpholino)phenyldiazonium tetrafluoroborate 
• 1147550-11-5 ammonium thiocyanate 
• 333-20-0 potassium thioacyanate 

Relevant articles and documents

Selective electrochemical: Para -thiocyanation of aromatic amines under metal-, oxidant- And exogenous-electrolyte-free conditions

An electrochemical oxidative para-C-H-thiocyanation of aromatic amines has been developed to construct thiocyanato aromatic compounds under metal-, oxidant-, and exogenous-electrolyte-free conditions in an undivided cell. The transformation is compatible

Metal-free late-stage C(sp2)-H functionalization of: N -aryl amines with various sodium salts

Metal-free consecutive C(sp2)-X (X = Cl, Br, S, N) bond formations of N-aryl amines (cyclic, fused, carbamate, and aminium radicals) were achieved under mild conditions using [bis(trifluoroacetoxy)iodo]benzene (PIFA) and simple nonharmful sodium salts. This direct and selective C(sp2)-H functionalization showed excellent functional group compatibility, cost effectiveness, and late-stage applicability for the synthesis of biologically active natural products. Two mechanisms were proposed to explain the ortho- or para-preference, as well as the accelerating effect of CH3NO2

1,1,2,2-Tetrahydroperoxy-1,2-Diphenylethane: An efficient and high oxygen content oxidant in various oxidative reactions

Several oxidative approaches namely thiocyanation of aromatic compounds, epoxidation of alkenes, amidation of aromatic aldehydes, epoxidation of α β-unsaturated ketones, oxidation of sulfides to sulfoxides and sulfones, bayer-villeger reaction, bromination and iodation of aniline and phenol derivatives oxidative esterification, oxidation of pyridines and oxidation of secondary, allylic and benzyllic alcohols were carried out using 1,1,2,2-Tetrahydroperoxy-1,2-Diphenylethane as the potential solid oxidant which can be stored for several months without any loss in its activity. All of the procedures were accomplished via mild reaction conditions and the products were afforded in high yields and short reaction times.