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326822-02-0

(2,9-dimethyl-4,7-diphenyl-1,10-phenantroline)NiBr2 is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 326822-02-0 Structure

  • Basic information

    1. Product Name: (2,9-dimethyl-4,7-diphenyl-1,10-phenantroline)NiBr2
    2. Synonyms:
    3. CAS NO:326822-02-0
    4. Molecular Formula:
    5. Molecular Weight: 578.956
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 326822-02-0.mol

  • Chemical Properties

    1. Melting Point: >300 °C
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (2,9-dimethyl-4,7-diphenyl-1,10-phenantroline)NiBr2(CAS DataBase Reference)
    10. NIST Chemistry Reference: (2,9-dimethyl-4,7-diphenyl-1,10-phenantroline)NiBr2(326822-02-0)
    11. EPA Substance Registry System: (2,9-dimethyl-4,7-diphenyl-1,10-phenantroline)NiBr2(326822-02-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 326822-02-0(Hazardous Substances Data)

326822-02-0 Usage

Uses

Catalyst for C-alkylation of nitroalkanes with unactivated alkyl iodides

Check Digit Verification of cas no

The CAS Registry Mumber 326822-02-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,2,6,8,2 and 2 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 326822-02:
(8*3)+(7*2)+(6*6)+(5*8)+(4*2)+(3*2)+(2*0)+(1*2)=130
130 % 10 = 0
So 326822-02-0 is a valid CAS Registry Number.

326822-02-0Upstream product

326822-02-0Downstream Products

326822-02-0Relevant articles and documents

Four-coordinated bipyridine complexes of nickel for ethene polymerization - The role of ligand structure

Kinnunen, Toni-J. J.,Haukka, Matti,Pakkanen, Tuula T.,Pakkanen, Tapani A.

, p. 257 - 262 (2000)

Four-coordinated bipyridine complexes of nickel, (2,2′-bipyridine)NiBr2 (1), (6,6′-dimethoxycarbonyl-2,2′-bipyridine)NiBr2 (2), (2,2′-biquinoline)NiBr2 (3) and (2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)NiBr2 (4), were synthesized. Single crystal X-ray structures were determined for compounds 2 and 4. Both structures were monoclinic with space group P21/c. For 2 a = 8.4289(7), b = 13.5013(14), c = 14.7341(15) ?, Z = 4. For complex 4 a = 12.8143(4), b = 22.5687(8), c = 7.8172(2) ?, Z = 4, respectively. Catalytic activities of complexes were studied in ethene polymerization using MAO as a cocatalyst. Complexes 2 and 3 showed a modest activity producing high-density polyethene. Polymerization temperature had a clear effect on the activities of the complexes. Reactions carried at 50°C yielded more polyethene than reactions at 30 or 70°. The effect of ligand structure on catalytic activity was also observed, the bulky substituents increased activity.

Nickel-Catalyzed C-Alkylation of Nitroalkanes with Unactivated Alkyl Iodides

Rezazadeh, Sina,Devannah, Vijayarajan,Watson, Donald A.

supporting information, p. 8110 - 8113 (2017/06/28)

Enabled by nickel catalysis, a mild and general catalytic method for C-alkylation of nitroalkanes with unactivated alkyl iodides is described. Compatible with primary, secondary, and tertiary alkyl iodides; and tolerant of a wide range of functional groups, this method allows rapid access to diverse nitroalkanes.

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