326882-81-9Relevant articles and documents
A practical synthesis of the first P-phosphinoylmethyl-λ5-phosphazenes
Alajarin,Lopez-Leonardo,Llamas-Lorente,Bautista
, p. 2085 - 2091 (2007/10/03)
The new N-aryl-P,P-diphenyl-P-(diphenylphosphinoyl)methyl-λ5-phosphazenes 2 have been prepared by three different approaches starting from the commercially available bis(diphenylphosphino)methane. Either oxidation of the mono-λ5-phosphazenes 3 or imination of the monoxide 4 yielded compounds 2 in moderate yields. The third method involved deprotonation of the easily accesible aminophosphonium salts 5.