32714-83-3Relevant academic research and scientific papers
Matrix isolation, spectroscopic characterization, and photoisomerization of m-xylylene
Neuhaus, Patrik,Grote, Dirk,Sander, Wolfram
, p. 2993 - 3000 (2008/09/18)
A new efficient synthesis of m-xylylene 1 is reported. The diradical 1 was trapped in argon matrices at 10 K and characterized by IR, UV-vis, and EPR spectroscopy. The syntheses reported before only allowed generation of 1 in organic glasses, and the spec
The mechanism of formation of m-xylylene type biradicals produced by photolysis of polymethyl benzenes or dihalomethyl benzenes
Haider,Migirdicyan,Platz,Soundararajan,Despres
, p. 733 - 738 (2007/10/02)
The mechanism of formation of the mesitylylene biradical (3) produced by short-wavelength photolysis of matrix-isolated mesitylene (1) has been investigated. The data rule out a mechanism involving the sequential formation of the biradical 3 via photolysi
Recent Studies of Meta-Xylylene and a Diaza Derivative
Haider, K. W.,Migirdicyan, E.,Platz, M. S.,Soundararajan, N.,Despres, A.
, p. 85 - 98 (2007/10/02)
A new photochemical precursor to meta-xylylene is reported and its mechanism of action is discussed.A diaza derivative of meta-xylylene is also reported.
