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Highly stable cage-like complexes by self-assembly of tetracationic Zn(II) porphyrinates and tetrasulfonatocalix[4]arenes in polar solvents
Fiammengo,Timmerman,De Jong,Reinhoudt
, p. 2313 - 2314 (2000)
Tetracationic Zn(II) porphyrinates and tetraanionic calix-[4]arenes can be assembled in polar solvents to obtain cage-like complexes in an entropy driven process. These structures are remarkably stable even in the presence of water or competing salts.
