327183-85-7Relevant academic research and scientific papers
Diastereoselective sulfonate-directed carbonyl reduction of γ-keto-sulfonates
McLaughlin, Noel,Duffy, Colm,Alletto, Francesco,Ravelli, Andrea,Lancianesi, Stefano,Gillick-Healy, Malachi,Adamo, Mauro F.A.
, p. 1313 - 1316 (2019)
The diastereoselective reduction of γ-keto-sulfonates to afford α,γ-substituted γ-hydroxy sulfonates has been investigated. Herein we report the first example of a diastereoselective carbonyl reduction whereby hydride attack is directed via chelation of a
3-oxopropane-1-sulphonic acids and sulphonates
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Page/Page column 7, (2008/06/13)
The invention relates to 1,3-disubstituted-3-oxopropane-1-sulfonic acids and sulfonates and enantiomerically inriched forms thereof. The invention further relates to the use of these enantiomerically inriched compounds to resolve mixtures of enantiomers, in particular mixtures of enantiomers of amino-functionalized compounds.
