32748-65-5

Upstream product

• 167628-04-8 N-[(2S,3S,6S)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-2-ethoxy-3,6-dihydro-2H-pyran-3-yl]-acetamide 
• 175722-70-0 Carbamic acid (2R,3R,6S)-2-(tert-butyl-dimethyl-silanyloxymethyl)-6-ethoxy-3,6-dihydro-2H-pyran-3-yl ester 
• 116455-00-6 Ethyl 6-O-(tert-butyldimethylsilyl)-2,3-dideoxy-α-D-threo-hex-2-enopyranoside 
• 23339-15-3 ethyl 2,3-dideoxy-α-D-erythro-hex-2-enopyranoside 
• 58888-62-3 ethyl 6-O-tert-butyldimethylsilyl-4-hydroxyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside 
• 124-63-0 methanesulfonyl chloride 

Relevant academic research and scientific papers

Synthesis of nitrogen-containing unsaturated carbohydrates via an allyl cyanate-to-isocyanate rearrangement

A new method for the synthesis of 4-amino-D-hex-2-enopyranosides and 2-amino-D-hex-3-enopyranosides has been developed. The key feature in this method involves construction of the allylamine moiety in the pyranose framework by employing an allyl cyanate-to-isocyanate rearrangement.