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ETHYL-(1-ISOCYANOCYCLOPROPYL)-CARBOXYLATE is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

32755-45-6

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32755-45-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 32755-45-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,2,7,5 and 5 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 32755-45:
(7*3)+(6*2)+(5*7)+(4*5)+(3*5)+(2*4)+(1*5)=116
116 % 10 = 6
So 32755-45-6 is a valid CAS Registry Number.
InChI:InChI=1/C7H9NO2/c1-3-10-6(9)7(8-2)4-5-7/h3-5H2,1H3

32755-45-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name ethyl 1-isocyanocyclopropane-1-carboxylate

1.2 Other means of identification

Product number -
Other names 1-Isocyan-1-cyclopropancarbonsaeure-ethylester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:32755-45-6 SDS

32755-45-6Relevant academic research and scientific papers

From isonitrile to nitrile via ketenimine intermediate: Palladium-catalyzed 1,1-carbocyanation of allyl carbonate by α-isocyanoacetate

Qiu, Guanyinsheng,Sornay, Charlotte,Savary, David,Zheng, Sheng-Cai,Wang, Qian,Zhu, Jieping

supporting information, p. 6966 - 6971 (2018/11/03)

A palladium-catalyzed 1,1-carbocyanation of allyl carbonate by α-quaternary α-isocyanoacetate was developed. Formation of ketenimine followed by homolysis of the C–N bond and recombination of the resulting caged radical pair was proposed to account for the formation of the unusual coupling product, the β-cyano-γ,δ-unsaturated ester.

Synthesis of new cyclopropylisonitriles and their applications in Ugi four-component reactions

Osipova, Anna,Yufit, Dmitrii S.,De Meijere, Armin

, p. 131 - 139 (2008/01/03)

Several new cyclopropylisonitriles were synthesized from the corresponding cyclopropylamines (41-69% yield) and utilized in Ugi four-component reactions to furnish 12 new dipeptides in 38-86% yield. The structures of four of these dipeptides were determined by X-ray crystallography. Georg Thieme Verlag Stuttgart.

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