32767-28-5Relevant academic research and scientific papers
Synthesis and reactivity of complexes 2a-c, their involvement as catalyst precursors for regioselective allylic substitution reactions and related [Ru(Cp*)Cl(Ph2POMe)(RCHCHCH2)] [PF6] η3-allyl ruthenium(IV)inter
Demerseman, Bernard,Renaud, Jean-Luc,Toupet, Loic,Hubert, Claudie,Bruneau, Christian
, p. 1371 - 1380 (2007/10/03)
The synthesis of the new complexes [Ru(Cp*)(L)(MeCN) 2]-[PF6] (L = Ph2POMe or Ph2P-o- tolyl) and {Ru(Cp*)-[Ph2PCH2C(tBu)=O](MeCN)}[PF 6] (2a-c) is achieved starting from [Ru(Cp*)
Regioselective allylic alkylation and etherification catalyzed by in situ generated N-heterocyclic carbene ruthenium complexes
Gürbüz, Nevin,?zdemir, Ismail,?etinkaya, Bekir,Renaud, Jean-Luc,Demerseman, Bernard,Bruneau, Christian
, p. 535 - 538 (2007/10/03)
Benzimidazolium halides are used for the first time as ligand precursors in ruthenium-catalyzed substitution of allylic carbonates and chlorides by carbon nucleophiles and phenols, respectively. After generation of diaminocarbene species upon deprotonatio
