32777-04-1Relevant academic research and scientific papers
Synthesis of F-alkyl α-hydroxy acids and esters from F-alkyl epoxides and F-alkyl α-bromo acids and esters from F-alkyl bromohydrins
Ould Amanetoullah,Chaabouni,Baklouti
, p. 149 - 153 (2007/10/03)
F-alkyl α-hydroxy acids and F-alkyl α-bromo acids were prepared respectively by the nitric acid ring-opening oxidative reaction of F-alkyl oxiranes, and oxidation by chromic acid of F-alkyl bromohydrins. The synthesized acids were converted to the corresponding methyl esters which may prove to be useful in the synthesis of F-alkylated heterocycles.
Laboratory-Scale Enzymatic/Chemical Syntheses of D- and L-β-Chlorolactic Acid and D- and L-Potassium Glycidate
Hirschbein, Bernard L.,Whitesides, George M.
, p. 4458 - 4460 (2007/10/02)
This paper describes preparations of D- (and L-) chlorolactic acids having enantiomeric excesses greater than 97percent by D- (and L-) lactate dehydrogenase catalyzed reduction of chloropyruvic acid with NADH.In syntheses carried out on 0.1-0.5 mol scales
