3278-94-2Relevant articles and documents
Substituted benzoyl (hetero) cyclic diones
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, (2008/06/13)
Substituted aryl or heteroaryl in particular benzoyl bicycloalkanediones and related compounds, intermediates therefor, synthesis thereof, and the use of said diones for the control of weeds.
Ring Enlargement with Diazomethane: Studies on Bridged Tricyclic 1,2-Diketones Based on Bicycloheptane/Bicyclooctane Systems Derived from Longifolene
Shitole, H.R.,Nayak, U.R.
, p. 415 - 417 (2007/10/02)
A comparative study of the ring enlargement by diazomethane of the bridged tricyclic 1,2-diketones based on bicycloheptane/bicyclooctane systems derived from longifolene, viz. longibornane-10,11-dione (longicamphorquinone, 4)/longihomocamphenilane-7,8-dione (longidione, 5) reveals a striking contrast.While 4 undergoes a facile ring homologation, 5 remains unchanged under the same conditions.The resulting isomeric keto-enol ethers 8/9 from 4, hydrolysable by acid to longihomocamphorquinone (12), have been further transformed into α,β-unsaturated ketones 10/11 by LAH reduction.