32780-31-7

Upstream product

• 64589-26-0 (+/-)-<(1,3/2,4,5)-5-acetamido-2,3,4-triacetoxycyclohexyl>-methyl acetate 
• 73410-97-6 2-O-β-D-glucopyranosyl-1L-(1,3,4/2,6)-4-amino-6-hydroxymethyl-1,2,3-cyclohexanetriol 
• 282101-84-2 (3aS,4S,6R,7R,7aS)-7-Methoxymethoxy-6-methoxymethoxymethyl-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-4-ylamine 
• 282101-79-5 (1R,2S,3R,6R)-6-Methoxymethoxy-5-methoxymethoxymethyl-cyclohex-4-ene-1,2,3-triol 
• 282101-80-8 (1S,2R,3R,6S)-6-Azido-3-methoxymethoxy-4-methoxymethoxymethyl-cyclohex-4-ene-1,2-diol 
• 282101-83-1 (3aS,4S,7R,7aS)-7-Methoxymethoxy-6-methoxymethoxymethyl-2,2-dimethyl-3a,4,7,7a-tetrahydro-benzo[1,3]dioxol-4-ylamine 
• 282101-82-0 (3aS,4R,7S,7aS)-7-Azido-4-methoxymethoxy-5-methoxymethoxymethyl-2,2-dimethyl-3a,4,7,7a-tetrahydro-benzo[1,3]dioxole 
• 282101-77-3 (4R,5S,6R)-4,5,6-Tris-(tert-butyl-dimethyl-silanyloxy)-2-hydroxymethyl-cyclohex-2-enone 
• 282101-78-4 (1R,4R,5S,6S)-4,5,6-Tris-(tert-butyl-dimethyl-silanyloxy)-2-hydroxymethyl-cyclohex-2-enol 
• 73619-28-0 DL-3,4-N,O-carbonyl-(1,3,4/2,6)-4-amino-6-hydroxymethyl-1,2,3-cyclohexanetriol 
• 73619-30-4 DL-3,4-N,O-carbonyl-1,7-O-isopropylidene-(1,3,4/2,6)-4-amino-6-hydroxymethyl-1,2,3-cyclohexanetriol 
• 73619-26-8 DL-(1,3,4/2,6)-4-benzyloxycarbonylamino-6-hydroxymethyl-1,2,3-cyclohexanetriol 
• 73619-36-0 1L-1,7-O-benzylidene-3,4-N,O-carbonyl-2-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-(1,3,4/2,6)-4-amino-6-hydroxymethyl-1,2,3-cyclohexanetriol 
• 32780-31-7 DL-validamine hydrochloride 

Downstream Products

• 86195-51-9 (-)-validamine hydrochloride 
• 68108-50-9 (1S)-(+)-(1,2,4/3,5)-1-acetamido-2,3,4-triacetoxy-5-acetoxymethylcyclohexane 
• 73410-97-6 1D-2-O-β-D-glucopyranosyl-(1,3,4/2,6)-4-amino-6-hydroxymethyl-1,2,3-cyclohexanetriol 
• 73410-97-6 2-O-β-D-glucopyranosyl-1L-(1,3,4/2,6)-4-amino-6-hydroxymethyl-1,2,3-cyclohexanetriol 
• 73619-36-0 1D-1,7-O-benzylidene-3,4-N,O-carbonyl-2-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-(1,3,4/2,6)-4-amino-6-hydroxymethyl-1,2,3-cyclohexanetriol 
• 73619-36-0 1L-1,7-O-benzylidene-3,4-N,O-carbonyl-2-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-(1,3,4/2,6)-4-amino-6-hydroxymethyl-1,2,3-cyclohexanetriol 
• 73619-26-8 DL-(1,3,4/2,6)-4-benzyloxycarbonylamino-6-hydroxymethyl-1,2,3-cyclohexanetriol 

Relevant academic research and scientific papers

SYNTHESIS OF β-D-GLUCOPYRANOSYLVALIDAMINE: 2-O-β-D-GLUCOPYRANOSYL-1L-(1,3,4/2,6)-4-AMINO-6-HYDROXYMETHYL-1,2,3-CYCLOHEXANETRIOL

β-D-Glucopyranosylvalidamine (1a), the structure of which was assigned to the degradation product of validamycin A, was synthesized by condensation of a protected validamine (8) with acetobromoglucose, followed by deblocking.Unexpectedly, 1a was found not to be identical with an authentic sample derived from the antibiotic