328119-67-1

Basic information

• Product Name: 2-Propenoic acid, 2-azido-, phenylmethyl ester
• CAS NO: 328119-67-1
• Molecular Formula: C10H9N3O2
• Molecular Weight: 203.2
• Mol File: 328119-67-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 2-azido-, phenylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 2-azido-, phenylmethyl ester(328119-67-1)
• EPA Substance Registry System: 2-Propenoic acid, 2-azido-, phenylmethyl ester(328119-67-1)

Safety Data

• Hazardous Substances Data: 328119-67-1(Hazardous Substances Data)

Upstream product

• 2495-35-4 benzylacrylate 
• 10288-11-6 Benzyl 2,3-dibromopropionate 

Downstream Products

• 328119-58-0 Benzyl 2H-azirine-3-carboxylate 
• 1007117-29-4 benzyl 4-acetyl-5-methyl-1H-pyrrole-3-carboxylate 
• 93009-44-0 2-benzyl 4-ethyl 5-methyl-1H-pyrrole-2,4-dicarboxylate 
• 328119-60-4 Benzyl 2-(5-methyl-2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)aziridine-2-carboxylate 
• 885686-69-1 (E)-benzyl 3-(2,6-dichlorophenyl)-2-(2-oxo-4-(2-oxooxazolidin-3-yl)but-3-enyl)aziridine-2-carboxylate 

Relevant articles and documents

Synthesis of polysubstituted N-H pyrroles from vinyl azides and 1,3-dicarbonyl compounds

(Chemical Equation Presented) Two synthetic methods for tetra- and trisubstituted N-H pyrroles are presented: (i) the thermal pyrrole formation by the reaction of vinyl azides with 1,3-dicarbonyl compounds via the 1,2-addition of 1,3-dicarbonyl compounds to 2H-azirine intermediates generated in situ from vinyl azides; (ii) the Cu(II)-catalyzed synthesis of pyrroles from α-ethoxycarbonyl vinyl azides and ethyl acetoacetate through the 1,4-addition reaction of the acetoacetate to the vinyl azides. By applying these two methods, regioisomeric pyrroles can be prepared selectively starting from the same vinyl azides.