328241-39-0Relevant articles and documents
Diastereoselectivity at chiral metal center of half-sandwich-type ruthenium complexes with planar-chiral cyclopentadienyl ligands in multiple ligand transfer reaction
Katayama, Taku,Onitsuka, Kiyotaka,Takahashi, Shigetoshi
, p. 2245 - 2256 (2007/10/03)
The triple ligand transfer reaction between planar-chiral cyclopentadienyl-ruthenium complexes [Cp′Ru(NCMe)3][PF6] (1) (Cp′ = 1-(COOR2)-2-Me-4-R1C5H2; R1 = Me, Ph, t-Bu) and iron
Multiple ligand transfer to planar-chiral cyclopentadienylruthenium complexes inducing metal-centered chirality
Katayama,Matsushima,Onitsuka,Takahashi
, p. 2337 - 2338 (2007/10/03)
Multiple ligand transfer reaction between planar-chiral cyclopentadienylruthenium complexes [Cp'Ru(AN)3][PF6] [(Cp' = 1-(CO2Et)-2-Me-4-RC5H2, R = Me, Ph, Bu(t), AN = acetonitrile] and iron complexes CpFe(CO)(L)X (L = PMe3, PPh3; X = I, Br) results in formation of metal-centered chiral ruthenium complexes Cp'Ru(CO)(L)X with a diastereoselectivity (de) up to 68%.